378 17 Enzymatic Synthesis and Modification of Glycolipids
Table 6.ß-Glucosidase-catalyzed glycolipid syntheses. Method 1: reverse hydrolysis; method 2: trans-
glycosylation.
ß-Glucosidase Alcohol Sugar Method Reference
Almond^1 Benzyl alcohol Glucose
Cellobiose
1
2
Marek et al., 1989
Almond^1 C 5 –C 12 Glucose 1 Vulfson et al., 1990a
Almond^1 C 5 –C 8 Methyl-ß-
glucoside,
Cellobiose,
Glucose
2
1
Vulfson et al., 1990b
Trichoderma viride C 7 ,C 8 Cellobiose 2 Shinoyama et al., 1991
Almond C 3 ,C 6 ,C 8 Glucose 1 Chahid et al., 1992
Almond C 8 Glucose 1 Ljunger et al., 1994
Almond Allyl alcohol, benzyl
alcohol
Glucose,
galactose
1 Vic and Crout, 1995
Almond 4-Hydroxybutanoic
acid-N-butylamide
Glucose
Cellobiose
1
2
Fischer et al., 1995
Pyrococcus
furiosus^1
4-Hydroxybutanoic
acid-N-butylamide
Cellobiose 2 Fischer et al., 1996
Almond,
Fusarium
oxysporum
C3–C 8 Glucose 1 Tsitsimpikou et al., 1996
Aspergillus niger C 1 ,C 2 Cellobiose 2 Yan and Liau, 1998
Almond^1 C 4 Glucose 1 Otto et al., 1998c
Almond^1 C 6 ,C 8 Glucose 1 Yi et al., 1998
Almond 2-(4-Methoxybenzyl)
-1-cyclohexanol
Glucose/
Phenyl-
ß-glucose
1/2 Zarevucka et al., 1999
Almond C 4 Glucose 1 Ismail et al., 1999b
(^1) Immobilized enzymes.