chemistry1

100 Synthetic Routes to Nitrate Esters 3.4.1.2 Vicinal dinitrate esters from the reaction of epoxides with dinitrogen pentoxide ...

236 Synthetic Routes toN-Nitro O 2 N CH 3 CH 3 CH 3 NNN NO 2 2 CH 3 NHNO 2 + 2 CH 2 O + CH 3 NH 2 + 2 H 2 O 185 Figure 5.81 The ...

Nitrate esters from strained oxygen heterocycles 101 co-workers^75 found it necessary to add aluminium chloride to the reaction ...

Primary nitramines as nucleophiles 237 N N N N N CH 2 N NO 2 NO 2 NO 2 NO 2 N N N CH 2 OAc NO 2 NO 2 197 N N N NN N NO 2 NO 2 NO ...

102 Synthetic Routes to Nitrate Esters Ceric ammonium nitrate (CAN) has been used for the synthesis ofβ-hydroxy nitrate esters f ...

238 Synthetic Routes toN-Nitro + 4 CH 2 O + H 2 N(CH 2 )nNH 2 N N N N N 2 )nN(CH NO 2 NO 2 NO 2 NO 2 HNO 3 , Ac 2 O 50–60 °C 205 ...

Nitrodesilylation 103 as the sole product (62 %), whereas longer reaction times with 4.0 equivalents of dinitrogen pentoxide yie ...

Primary nitramines as nucleophiles 239 5.13.3 Condensations with formaldehyde 2 RNHNO 2 + CH 2 O 90 % H 2 SO 4 + H 2 O 212, R = ...

104 Synthetic Routes to Nitrate Esters Trimethylsilyl ethers and other simplen-alkylsilyl ethers give high yields of nitrate est ...

240 Synthetic Routes toN-Nitro An interesting reaction has been reported for the synthesis of polymethylenenitramines and also i ...

Additions to alkenes 105 3.6.2 Nitrogen oxides N 2 O 4 , O 2 51 + + R R R R C R R R R O 2 N Et 2 O, 0 °C C NO 2 52 C R R R R O 2 ...

Aromatic nitramines 241 N H 3 C CH 3 N H 3 C CH 3 NO 2 NO 2 227 N H 3 C NO 2 NO 2 229 NH H 3 C NO 2 NO 2 230 N H 3 C NO 2 NO 2 N ...

106 Synthetic Routes to Nitrate Esters Canfield and Rohrback^106 reported on the reaction of some electron-deficient difluo- roa ...

242 Synthetic Routes toN-Nitro acid.^177 This route is favoured on both industrial and laboratory scales – the two nitro groups ...

Miscellaneous methods 107 R NH 2 R ONO 2 -15 °C to -10 °C CH 3 CN, NO 2 F R = alkyl, FC(NO 2 ) 2 CH 2 , FC(NO 2 ) 2 CH 2 CH 2 Fi ...

The nitrolysis of hexamine 243 The phenol (237) can be synthesized via a Mannich condensation between phenol, formalde- hyde and ...

108 Synthetic Routes to Nitrate Esters 3.9 Synthetic routes to some polyols and their nitrate ester derivatives CH 3 NO 2 + 3 CH ...

244 Synthetic Routes toN-Nitro of composite explosives like Composition B, Torpex, Cyclotols, DBX, HBX, Hex-24, PTX-1 etc. and p ...

Synthetic routes to polyols and derivatives 109 on nitration with mixed acid. Metriol trinitrate (MTN) is a practical explosive ...

The nitrolysis of hexamine 245 is much more efficient than method 5.15.1.1 and works on the principle that one mole of hexamine ...