chemistry1

Dibenzotetraazapentalenes 325 NH 2 NH 2 N H 2 N NH 2 222 N N 3 N 3 223 N N N N 3 N N N O 2 N N N N N NO 2 NO 2 O 2 N O 2 N N N N ...

5 Synthetic Routes toN-Nitro Functionality 5.1 Introduction Aromatic and aliphatic nitro compounds are of huge industrial import ...

326 N-Heterocycles z-TACOT (225) and y-TACOT (231) are single isomers but their syntheses are rather long for cost effective com ...

192 Synthetic Routes toN-Nitro Nitrimines are a relatively minor group ofN-nitro compound. The nitro derivatives of guanidine an ...

References 327 and R. J. Spear, ‘Synthesis of Organic Energetic Compounds’, inOrganic Energetic Compounds, Ed. P. L. Marinkas, N ...

Nitramines, nitramides and nitrimines as explosives 193 N N N NO 2 O 2 N NO 2 N NN N NO 2 O 2 N NO 2 O 2 N NN N NN NO 2 NO 2 NO ...

328 N-Heterocycles I. S. Abdrakhmanov, G. K. Khisamutdinov, I. Z. Kondyukov, V. L. Korolev, S. F. Melnikov, T. A. Mratkhuzina, ...

194 Synthetic Routes toN-Nitro Some compounds containing the secondary nitramide group have found limited use as ex- plosives.N, ...

References 329 B. Chen, J. Li and Y. Ou, ‘Modified Preparation and Nitration of 3-Picrylamino-1,2,4-triazole’, inProc. 17th Int ...

Direct nitration of amines 195 5.3 Direct nitration of amines 5.3.1 Nitration under acidic conditions R NHNO 2 H+ RNN OH O N 2 O ...

330 N-Heterocycles M. D. Coburn,J. Heterocycl. Chem., 1973, 10 , 743. J. L. Flippen-Anderson, R. D. Gilardi, A. M. Pitt and W. ...

196 Synthetic Routes toN-Nitro low basicity i.e. those containing one or more nitro groups on the aromatic ring (Table 5.1, Entr ...

References 331 G. A. Buntain, M. D. Coburn, B. W. Harris, M. A. Hiskey, K. -Y. Lee and D. G. Ott,J. Heterocycl. Chem., 1991, 28 ...

Direct nitration of amines 197 The directN-nitration of the amino groups of the hexahydrotriazine (23) is only possible due to t ...

332 ...

198 Synthetic Routes toN-Nitro have been reported and these are discussed in Chapter 6 together with other energetic bicyclic an ...

8 Miscellaneous Explosive Compounds The vast majority of organic compounds finding wide use as commercial or military explo- siv ...

Direct nitration of amines 199 acceptable yield.^3 Some nitramines can be prepared via the sole addition of zinc chloride to a s ...

334 Miscellaneous Explosive Compounds OH O O HO O O O O Cl O O O O N 3 2 ClCH 2 CH 2 OH H 2 SO 4 , PhCH 3 90 % 1 2 (BAEA) EtOH, ...

200 Synthetic Routes toN-Nitro One simple example of chloride-catalyzed nitration is the synthesis of the energetic plasti- cize ...