chemistry1

150 Synthetic Routes to AromaticC-Nitro Compounds Peroxydisulfuric acid (H 2 S 2 O 8 ) is one of the most powerful peroxyacid ox ...

286 Nitramines and Their Derivatives Ammonium dinitramide (152) is synthesized by treating a solution of ammonium ni- trourethan ...

Oxidation of arylamines, arylhydroxylamines and other derivatives 151 Table 4.1 Oxidation of arylamines and their derivatives wi ...

Energetic groups 287 AlkylN,N-dinitramines (154) have been prepared from the reaction of the tetraalkylam- monium salts (155) of ...

152 Synthetic Routes to AromaticC-Nitro Compounds protection as theirN-acetyl orN,N′-diacetyl derivatives. Thus, pentanitrotolue ...

288 Nitramines and Their Derivatives amines have no quaternary nitrogen and have the negative charge counterbalanced with a posi ...

Oxidation of arylamines, arylhydroxylamines and other derivatives 153 Table 4.2 Oxidation of arylamines with peroxycarboxylic ac ...

154 Synthetic Routes to AromaticC-Nitro Compounds Azo and azoxy compounds are potential by-products of peroxyacetic acid oxidati ...

References 289 C. L. Coon, ‘Research on the Synthesis of Heterocyclic Explosives’, inProc. International Sympo- sium on Pyrotec ...

Oxidation of arylamines, arylhydroxylamines and other derivatives 155 Dimethyldioxirane is a powerful oxidant prepared as a solu ...

290 Nitramines and Their Derivatives M. D. Coburn, B. W. Harris, H. H. Hayden, K. Y. Lee and M. M. Stinecipher,Ind. Eng. Chem. ...

156 Synthetic Routes to AromaticC-Nitro Compounds Table 4.3 Oxidation of arylhydroxylamines with ozone (ref. 39) NHOMe NO 2 NHOH ...

References 291 R. J. Spear and W. S. Wilson,J. Energ. Mater., 1984, 2 , 61. I. J. Dagley and R. J. Spear, inOrganic Energetic C ...

Nucleophilic aromatic substitution 157 fromN-hydroxy-2,4,6-trinitroaniline. The synthesis of 1,2,4,5-trinitrobenzene from the ni ...

292 ...

158 Synthetic Routes to AromaticC-Nitro Compounds 4.8.1 Displacement of halide 4.8.1.1 Substrate reactivity X (NO 2 )n X = I, Br ...

7 Energetic Compounds 3: N-Heterocycles 7.1 Introduction Until the end of the First World War the main filling for mass ordnance ...

Nucleophilic aromatic substitution 159 Cl NO 2 NO 2 N NO 2 NO 2 O 2 N O 2 N O 2 N O 2 N R R' OH NO 2 NO 2 NH 2 NO 2 NO 2 O 2 N O ...

294 N-Heterocycles easy to synthesize and, coupled with their high performance, it is probable that some of these compounds may ...

160 Synthetic Routes to AromaticC-Nitro Compounds 2,2′,4,4′,6,6′-Hexanitroazobenzene (HNAB) (90), an explosive exhibiting therma ...