Physical Chemistry Third Edition

602 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics EXAMPLE13.9 Evaluate the concentration overpotential ...

13.5 Nonequilibrium Electrochemistry 603 (a) Reaction coordinate –(1–a)nF(– 8 ) nF(– 8 ) nF(– 8 ) V (b) (c) Reaction c ...

604 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics amount equal to−nF(φ−φ◦), wherenis the number of elec ...

13.5 Nonequilibrium Electrochemistry 605 nFk◦exp [ ( 1 −α)nF ( φeq−φ◦ ) RT ] [R]bnFk◦exp [ − αnF ( φeq−φ◦ ) RT ] [O]b (13.5-15) ...

606 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics –60 –10 –5 0 5 10 –40 –20 0 20 /mV j/j 0 ja jnet jc 4 ...

13.5 Nonequilibrium Electrochemistry 607 Butler–Volmer equation, Eq. (13.5-22), is much larger than the first term, and |j|≈j 0 ...

608 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics For a current density of 0.01 A cm−^2 and a hydrogen ...

13.6 Experimental Molecular Study of Chemical Reaction Mechanisms 609 Detection of Reactive Intermediates If a reactive intermed ...

610 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics trap.^37 Molecular oxygen also reacts with free radic ...

13.6 Experimental Molecular Study of Chemical Reaction Mechanisms 611 EXAMPLE13.10 If the distance between the two disks in Figu ...

612 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics of the other halogens. The reactant molecules pass in ...

13.6 Experimental Molecular Study of Chemical Reaction Mechanisms 613 05 Emission intensity v = 3→ 2 transitions 10 t/ms 15 20 P ...

614 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics laser study, in which it was verified that there is a ...

13.6 Experimental Molecular Study of Chemical Reaction Mechanisms 615 PROBLEMS Section 13.6: Experimental Molecular Study of Che ...

616 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics 13.42 a.Write a computer program to integrate the thr ...

3 The Molecular Nature of Matter ...

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14 Classical Mechanics and the Old Quantum Theory PRINCIPAL FACTS AND IDEAS The molecular nature of matter is studied through q ...

620 14 Classical Mechanics and the Old Quantum Theory 14.1 Introduction Part 1 of this textbook presents the study of the macros ...

14.2 Classical Mechanics 621 14.2 Classical Mechanics According to classical mechanics, the state of a system is specified by gi ...