Physical Chemistry Third Edition

522 11 The Rates of Chemical Reactions Some techniques were presented for studying fast reactions that cannot be studied by clas ...

12 Chemical Reaction Mechanisms I: Rate Laws and Mechanisms PRINCIPAL FACTS AND IDEAS Nearly every chemical reaction proceeds b ...

524 12 Chemical Reaction Mechanisms I: Rate Laws and Mechanisms 12.1 Reaction Mechanisms and Elementary Processes in Gases Most ...

12.1 Reaction Mechanisms and Elementary Processes in Gases 525 that lead to chemical reaction in a gas-phase bimolecular element ...

526 12 Chemical Reaction Mechanisms I: Rate Laws and Mechanisms whered 12 is the collision diameter for substance 1 and substanc ...

12.2 Elementary Processes in Liquid Solutions 527 Termolecular Gas-Phase Reactions A termolecular elementary process in the gas ...

528 12 Chemical Reaction Mechanisms I: Rate Laws and Mechanisms The rapidity of some liquid-state reactions at first seems surpr ...

12.2 Elementary Processes in Liquid Solutions 529 constitutes a diffusion flux that obeys Fick’s law of diffusion. It is assumed ...

530 12 Chemical Reaction Mechanisms I: Rate Laws and Mechanisms Solution k 4 π(6. 02 × 1023 mol−^1 )(4. 2 × 10 −^9 m^2 s−^1 )(4 ...

12.2 Elementary Processes in Liquid Solutions 531 The reaction diameter for the reaction between hydrogen ions and hydroxide ion ...

532 12 Chemical Reaction Mechanisms I: Rate Laws and Mechanisms Solution reactions that are much slower than diffusion-limited r ...

12.3 The Temperature Dependence of Rate Constants 533 reaction of part a and the value of the rate constant at 40 ◦C. State any ...

534 12 Chemical Reaction Mechanisms I: Rate Laws and Mechanisms EXAMPLE12.6 For the gas-phase reaction H 2 +I 2 −→2HI at 373.15 ...

12.3 The Temperature Dependence of Rate Constants 535 The Collision Theory of Bimolecular Elementary Gas-Phase Reactions The pri ...

536 12 Chemical Reaction Mechanisms I: Rate Laws and Mechanisms speed, the minimum relative speed that can lead to reaction: v&g ...

12.3 The Temperature Dependence of Rate Constants 537 EXAMPLE12.7 For the reaction of Example 12.6, calculate the fractional cha ...

538 12 Chemical Reaction Mechanisms I: Rate Laws and Mechanisms EXAMPLE12.8 Assuming the activation energy and the value of the ...

12.3 The Temperature Dependence of Rate Constants 539 The activation energies are somewhat smaller than for activation-limited r ...

540 12 Chemical Reaction Mechanisms I: Rate Laws and Mechanisms 12.11The gas-phase decomposition of acetaldehyde, CH 3 CHO, obey ...

12.4 Reaction Mechanisms and Rate Laws 541 be incorrect. If they match, the mechanism might be correct, although other mechanism ...