Physical Chemistry Third Edition

1042 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States Table 25.1 Vibrational States fo ...

25.1 The Quantum Statistical Mechanics of a Simple Model System 1043 Postulate 2. All system microstates of equal energy are equ ...

1044 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States over system microstates. Themean ...

25.1 The Quantum Statistical Mechanics of a Simple Model System 1045 Table 25.2 Average, Most Probable, and Boltzmann Proba- bil ...

1046 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States where we must require thata<1 ...

25.2 The Probability Distribution for a Dilute Gas 1047 25.4 Consider a system of four distinguishable rigid rotating diatomic m ...

1048 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States The molecules in our system are ...

25.2 The Probability Distribution for a Dilute Gas 1049 and the most probable distribution resembled each other. Although we do ...

1050 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States for the first pick, there areg−1 ...

25.2 The Probability Distribution for a Dilute Gas 1051 Exercise 25.8 Find the percent error in approximating Eq. (25.2-10) by E ...

1052 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States the maximum value ofW({N}) can b ...

25.2 The Probability Distribution for a Dilute Gas 1053 For ln(N!) ln(N!)≈ 1 2 ln(2πN)+Nln(N)−N (25.2-20) Stirling’s approximati ...

1054 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States Equations (25.2-24) and (25.2-25 ...

25.3 The Probability Distribution and the Molecular Partition Function 1055 negligible. The potential energy of two molecules ca ...

1056 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States The most probable distribution c ...

25.3 The Probability Distribution and the Molecular Partition Function 1057 The Molecular Partition Function of a Dilute Monatom ...

1058 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States wheremis the molecular mass. We ...

25.3 The Probability Distribution and the Molecular Partition Function 1059 0123456 7 Curve representing the function exp( 2 h^ ...

1060 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States EXAMPLE25.3 Find the value ofztr ...

25.3 The Probability Distribution and the Molecular Partition Function 1061  4(0.02018 kg mol−^1 )(1.00 m)^2 (1. 3807 × 10 −^23 ...