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AROMATIC NITRO COMPOUNDS 209 The nature of the Janovsky’s colour reaction is not sufficiently understood. Reitzenstein and Stamm ...

210 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES It was considered originally to be a tautomer of the picrate. More recently, by treat ...

AROMATIC NITRO COMPOUNDS 211 (30) IX X X = H, OH, Cl Y = H, NO 2 This mechanism was suggested by Ishidata and Sagakuchi [68]. Th ...

212 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES with an 0.1 N solution of sodium colamate. The nitro compound behaves as a Lewis acid ...

AROMATIC NITRO COMPOUNDS 213 Owing to this, an acrydane, for example, can be converted under the influence of m- dinitrobenzene ...

214 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES The mobile electron is most likely that associated with the free valency on the N ato ...

AROMATIC NITRO COMPOUNDS 215 Stopping the polymerization consisted here in the formation of a nitro compound (I) and an ether (I ...

216 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES The next stage would be the formation of the nitroso compound: (36b) VI VII Next, var ...

AROMATIC NITRO COMPOUNDS 217 in the vulcanization of rubber is limited to butyl rubber, as may be seen from the patent literatur ...

218 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES phenolic group in o- nitrophenol is not capable of molecular association, unlike m- a ...

AROMATIC NITRO COMPOUNDS 219 haved abnormally, as its molecular weight increased with the increase of the con- centration of sol ...

220 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES toluene becomes more intense under the influence of sulphuric acid. That is ascribed ...

AROMATIC NITRO COMPOUNDS 221 are dissolved in solution to a considerable extent. All this would be impossible if they were forme ...

222 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES tween A and B (Buehler et al. [130]). This would explain the superiority of trinitro- ...

AROMATIC NITRO COMPOUNDS^223 He also studied the effect of the solvent and found that it should not be neg- lected : Heats of fo ...

224 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES This means that steric barriers exist which must be overcome to form an addition comp ...

AROMATIC NITRO COMPOUNDS 225 OTHER REACTIONS OF NITRO COMPOUNDS All aromatic. nitro compounds yield chloropicrin when treated wi ...

226 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES H. J. BACKER, Rec. trav. chim. 69, 610 (1950). W. G. H. EDWARDS, Chem. and Ind. 1951 ...

AROMATIC NITRO COMPOUNDS 227 46a. F. HABER and J. WEISS, Proc. Roy. Soc. A, 147, 332 (1934). 46b. H. LOEB, G. STEIN and J. WEISS ...

228 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES D. H. HEY, J. Chem. Soc. 1934, 1966. D. H. HEY and G. S. MISRA, Faroday Soc. Discuss ...