Synthetic Inorganic Chemistry

110 THE THEORY OF IONIZATION Neither the acid nor the base alone furnishes many ions, but when they are mixed, the H+ and OH" io ...

METATHESIS 111 This type of reaction is particularly interesting when the salt of the weak acid is sparingly soluble. Ferrous su ...

112 THE THEORY OF IONIZATION is large, the amount of NH 3 necessary to produce equilibrium is small. Such a substance as pure am ...

METATHESIS 113 water gives a red suspension. Upon adding HC1 this red powder very slowly dissolves (much more slowly than copper ...

114 THE THEORY OF IONIZATION Formation of Volatile Products. When a product of a reaction is volatile it has a tendency to escap ...

HYDROLYSIS 115 HYDROLYSIS The ionization of water is so slight that often it can be totally disregarded. It cannot be neglected, ...

116 THE THEORY OF IONIZATION more of the acid to ionize. This cycle of operations repeats itself until we have the same state of ...

IONIZATION OF POLYBASIC ACIDS 117 When the hydrolysis of the salt of a polybasic acid is considered, the different H radicals mu ...

118 THE THEORY OF IONIZATION COMPLEX IONS Ammoniates. Review what was said in Chapter II about water of crystallization and hydr ...

COMPLEX IONS 119 If the two sets of ionic equations are now put together it is seen that 2NH 4 + and 2OH ~ have been left and th ...

120 THE THEORY OF IONIZATION When another equivalent of sodium cyanide is added the pre- cipitate entirely redissolves. In this ...

REACTIONS OF OXIDATION AND REDUCTION 121 PROBLEMS Describe observable effects and write the fully ionized equa- tion for the fol ...

122 THE THEORY OF IONIZATION charges the positive charges of the metal ions, we can eliminate them from the equation, which then ...

EEACTIONS OF OXIDATION AND REDUCTION 123 to another; metathesis involves no transfer of charges, but simply a regrouping of the ...

124 THE THEORY OF IONIZATION trons flow into the cell from the metallic conductor, reduction occurs. At the anode, which is the ...

REACTIONS OF OXIDATION AND REDUCTION 125 the cathode. If the anode were of an unattackable material, such as platinum, the curre ...

126 THE THEORY OF IONIZATION that part of the circuit. The passage of Zn++ ions through the porous wall in one direction and of ...

LAW OF MOLECULAR CONCENTRATION 127 temperatures. The word molecule here signifies any individual component whether electrically ...

128 THE THEORY OF IONIZATION in which k 2 is likewise a constant which depends on the chemical affinities of C and D and natural ...

LAW OF MOLECULAR CONCENTRATION 129 ide and its dissociation products at a temperature above 500°. 2SO 3 ^± 2SO 2 + O 2 The veloc ...