inorganic chemistry

functions, for potential applications in optically addressable mat- erials. The question is how much we can rationalize the beha ...

functionalities of the single subentities(3,4). Nowadays, one of the most striking goals is to provide building blocks that can ...

such as micelles, vesicles, and gels, and finish with crystalline materials. Along our journey, we will elaborate on design feat ...

density shift, they can be considered either as metal-to-ligand charge-transfer (MLCT) or ligand-to-metal charge-transfer (LMCT) ...

Usually, absorption and emission of light between states of dif- ferent multiplicity are spin-forbidden. However, due to the mix ...

If compared with their Ru(II) analogues, Os(II) complexes dis- play smaller gaps between the ground and the excited electronic s ...

to excited electronic states that involve more than one molecular entity. For the monomeric species, either LC or MLCT excited s ...

trans-isomer of 1-[10-(4-phenyl-azophenixy)decyl]pyridinium bromide (namely,AzoC10) can be well recognized bya-CD, due to favora ...

b-Cyclodextrines, appended to a ruthenium complex, have been employed as hosts for iridium and osmium complexes bear- ing adaman ...

An interesting self-assembled light-harvesting antenna system based on a ruthenium complex and a Nd(III) emitter has been report ...

namely,Ru-CandOs-G, respectively. In polar nonprotic solvent, that is, CH 2 Cl 2 , these compounds are able to associate in pair ...

B. MICELLES ANDVESICLES An interesting approach to have multiple components non- covalent assembled, based on identical or diffe ...

optoelectronics (57,58), magnetic materials (59,60), liquid crystals ( 61 – 63 ), templates of mesoporous materials (64,65), bio ...

synthesis of ruthenium(52,100,101), rhenium- ( 102 ), and iron- based amphiphiles ( 103 ). Further, Bruceet al. have correlated ...

Despite most of the investigations on the ruthenium complexes containing micelles deal with the quenching phenomena, there are f ...

To compare the properties of the metallosurfactants upon aggregation, the photophysical characteristics of the complexes 9 – 13 ...

a drop of ethanol into then-hexane was added to disassemble the aggregates. The biexponential decays turned in a monoexponential ...

the reduction of the vibrational modes available to the head groups within the confined environment of the aggregate. Upon combi ...

(CMC¼9 mM) was used. The nonluminescent cationic surfactant seemed to play a noninnocent role. Indeed for concentration of CTAB ...

C. DOUBLECOMPLEXSALTS Iridium(III) complexes have been widely explored in the past few decades because of their outstanding phot ...