The Chemistry Maths Book, Second Edition

(Grace) #1

634 Solutions to exercises



  1. (i)ln 16 (ii)ln 1223 (iii)ln 132


(iv)ln 12



  1. (i)ln 1 x


2

(ii)ln(2x 1 − 1 3) (iii) 0


(iv)x (v)x


2










  1. (i)0.2310 s (ii)0.6931 1 × 110


5

s


Chapter 4


Section 4.2


1.∆y 1 = 13 x


2

∆x 1 + 13 x(∆x)


2

1 + 1 (∆x)


3


  1. (i)


(ii)



  1. (i)


(ii)


Section 4.3


4.x 1 = 1 − 1 , essential 5.x 1 = 10 , removable


6.x 1 = 13 , essential;x 1 = 10 , removable


Section 4.4



  1. 0 8.±∞ 9. 123 10. 122

  2. 1 12. 0 13.∞ 14.− 4

  3. 2 16.−ln 12 17.−ln 13


Section 4.5
























=− +



−=−


−− −

y


x


e


x


e


dy


dx


e


xx x

2



  • ,




=


+∆+∆


+∆ +


=


y


x


xxx x


xx x


dy


dx


x


33 3


2


22

32 32

1

()


()


,


22



=−


+∆


+∆


=−


y


x


xx


xx x


dy


dx


x


42 4


22 3

()


,


dy


dx


= 4 x


3



=+∆+∆+∆


y


x


46 4xxxxx x


32 2 3

()(),




=++∆ =+


y


x


xx


dy


dx


432 , 43 x


lim


()


∆p
p

K


Kp





=






0


1


2

θ


∆=













++∆








θ


Kp


11()Kp K p p


lim


∆x


y


x


x





=


0


3


2



=+∆+∆


y


x


33 xxx x


22

()


p


p


= RT











o

o

γ


exp [(μμ) 2 ]


h


RT


Mg


p


p


=−










ln


0

Section 4.6



  1. 3 x


2

24.(5 2 4)x


124

25.(1 2 3)x


− 223

26.− 32 x


4

27.− 21 + 16 x 1 − 112 x


2

1 + 151 cos 1 x 1 + 161 sin 1 x 1 + 17 e


x

1 − 182 x


28.nRT(2nB 1 − 1 V) 2 V


3

29.−(1 1 − 14 x


2

) 1 sin 1 x 1 − 18 x 1 cos 1 x


30.(5 1 + 13 x)e


x

31.(cos 1 x 1 − 1 sin 1 x)e


x



  1. 11 + 1 ln 1 x








35.−cosec


2

x 36.(1 1 − 1 ln 1 x) 2 x


2

37.5(1 1 + 1 x)


4












  1. 41 cos 14 x 42.− 2 e


− 2 x









45.−(4x 1 − 1 3)sin(2x


2

1 − 13 x 1 + 1 1)


46.cos 1 xe


sin 1 x

47.−tan 1 x
















52.cos 1 x 1 cos 12 x 1 − 121 sin 1 sin 12 x



  1. 41 cos


2

12 x 1 sec


2

14 x 1 − 121 tan 14 x 1 sin 14 x




































Section 4.7














xy


xxy



(ln)1+



32 +


3


2

x


y



x


y


2


1


4

x


−x


2


14


2


  • x


1


xx() 1 +


2


1


4

x


+x


2


14


2

− x













1

2

32

2 na


V


nRT


()Vnb



()Vnb−


p







V


nRT V nB


3

() 2


1


43 y−


34


2


2

232

xx


x


()


()










22


22 3

2

xxe


x

(1+


+

)


62


3


22


12

2

12

xx


x


x


()


()


++






sin cos


sin sin


22 2


2


2

xx


xx










1


2


1




  • 3






xx−


6sin(3


cos(3

xx e


22 x

2


2





−+

)


)

43


231


2

x


xx



−+


(4 3)xe


xx


231 −+

2

−−


−−


34 3


22 3 1


232

()


()


x


xx


2


3


22

x


()−x


x


2 x


2






814 +−


2

2

xx x x


x


sin ( )cos


sin


618 3 4 3


3


234

32

+−−−






xx x x


()x

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