Physical Chemistry Third Edition

422 9 Gas Kinetic Theory: The Molecular Theory of Dilute Gases at Equilibrium PROBLEMS Section 9.7: The Model System with Potent ...

9.8 The Hard-Sphere Gas 423 Table A.15 in the appendix gives the values of the effective hard-sphere diameters of several substa ...

424 9 Gas Kinetic Theory: The Molecular Theory of Dilute Gases at Equilibrium whereVm/n, the molar volume, where we define the ...

9.8 The Hard-Sphere Gas 425 EXAMPLE9.17 Obtain a formula for the second virial coefficient of a hard-sphere gas. Solution For th ...

426 9 Gas Kinetic Theory: The Molecular Theory of Dilute Gases at Equilibrium Molecular Collisions in a Hard-Sphere Gas We now w ...

9.8 The Hard-Sphere Gas 427 and denoted byλ. This volume is (volume containing one particle)λπd^2 (9.8-11) and must equalV/N, t ...

428 9 Gas Kinetic Theory: The Molecular Theory of Dilute Gases at Equilibrium The relative speed is the rate of change ofrand is ...

9.8 The Hard-Sphere Gas 429 Solution a. N  N V  6. 022 × 1023 mol−^1 0 .02445 m^3 mol−^1  2. 463 × 1025 m−^3 〈v〉 ( 8(8.3145 ...

430 9 Gas Kinetic Theory: The Molecular Theory of Dilute Gases at Equilibrium square root of the absolute temperature. For examp ...

9.8 The Hard-Sphere Gas 431 1 x^1 r y 2 2 Figure 9.21 An “Average” (Right-Angle) Collision of Two Hard Spheres of Different Type ...

432 9 Gas Kinetic Theory: The Molecular Theory of Dilute Gases at Equilibrium EXAMPLE9.20 Calculate the mean relative speed of n ...

9.8 The Hard-Sphere Gas 433 be easy to remember because all four factors are things to which the rate should be proportional. Th ...

434 9 Gas Kinetic Theory: The Molecular Theory of Dilute Gases at Equilibrium temperature of 298.15 K. The effective hard-sphere ...

9.9 The Molecular Structure of Liquids 435 has a nearest-neighbor distance equal to 372 pm. This distance is slightly smaller th ...

436 9 Gas Kinetic Theory: The Molecular Theory of Dilute Gases at Equilibrium Solution 〈v〉 √ 8 RT πM  √ 8(8.3145 J K−^1 mol−^1 ...

9.9 The Molecular Structure of Liquids 437 The probability distribution for molecular speeds is fv(v) 4 π ( m 2 πkBT ) 3 / 2 v^ ...

438 9 Gas Kinetic Theory: The Molecular Theory of Dilute Gases at Equilibrium the total pressure 2.000 atm. Find the total numbe ...

9.9 The Molecular Structure of Liquids 439 j.The mean value of a velocity component is equal to the mean speed of the molecules ...

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10 Transport Processes PRINCIPAL FACTS AND IDEAS The macroscopic description of nonequilibrium states of fluid systems requires ...