Physical Chemistry Third Edition

482 10 Transport Processes PROBLEMS Section 10.5: Transport in Electrolyte Solutions 10.50Calculate the transference numbers for ...

10.5 Electrical Conduction in Electrolyte Solutions 483 ADDITIONAL PROBLEMS 10.58The thermal conductivity, viscosity, and self-d ...

484 10 Transport Processes e.A smaller ion will always have a smaller effective radius in aqueous solution. f.If the elapsed tim ...

11 The Rates of Chemical Reactions PRINCIPAL FACTS AND IDEAS The rate of a chemical reaction depends on the concentrations of t ...

486 11 The Rates of Chemical Reactions 11.1 The Macroscopic Description of Chemical Reaction Rates In this chapter we discuss th ...

11.1 The Macroscopic Description of Chemical Reaction Rates 487 oscillatory reactions do exist.^2 Figure 11.1 shows schematicall ...

488 11 The Rates of Chemical Reactions PROBLEMS Section 11.1: The Macroscopic Description of Chemical Reaction Rates 11.1 Consid ...

11.2 Forward Reactions with One Reactant 489 First-Order Reactions Consider a reaction at constant temperature of a single react ...

490 11 The Rates of Chemical Reactions is found to be first order. The rate constant at 337.6 K is equal to 5. 12 × 10 −^3 s−^1 ...

11.2 Forward Reactions with One Reactant 491 Solution k ln(2) t 1 / 2  ln(2) 7. 1 × 108 yr  9. 8 × 10 −^10 yr−^1 τ 1 k  1 9 ...

492 11 The Rates of Chemical Reactions EXAMPLE11.3 The gas-phase reaction NO 3 −→NO 2 + 1 2 O 2 obeys second-order kinetics. At ...

11.2 Forward Reactions with One Reactant 493 b.Find the half-life of the reaction of the previous example if the initial concent ...

494 11 The Rates of Chemical Reactions Exercise 11.8 a.Verify Eq. (11.2-18). b.Find the units of the rate constantkffor annth-or ...

11.2 Forward Reactions with One Reactant 495 graph. Denote the reactant by A. To test for zero order, one makes a graph of[A]t a ...

496 11 The Rates of Chemical Reactions Determination of Reaction Order Using the Half-Life You can carry out several experiments ...

11.2 Forward Reactions with One Reactant 497 The Method of Initial Rates In this method we compare data directly with the rate l ...

498 11 The Rates of Chemical Reactions PROBLEMS Section 11.2: Forward Reactions with One Reactant 11.3A hypothetical chemical re ...

11.3 Forward Reactions with More Than One Reactant 499 equal to 696 s. Find the order of the reaction and the value of the rate ...

500 11 The Rates of Chemical Reactions whereaandbrepresent stoichiometric coefficients and where A and B represent chemical form ...

11.3 Forward Reactions with More Than One Reactant 501 This is the same as 1 [A]t − 1 [A] 0 kfbt (11.3-8) where we drop the pri ...