Organic Chemistry of Explosives
288 Nitramines and Their Derivatives amines have no quaternary nitrogen and have the negative charge counterbalanced with a posi ...
References 289 C. L. Coon, ‘Research on the Synthesis of Heterocyclic Explosives’, inProc. International Sympo- sium on Pyrotec ...
290 Nitramines and Their Derivatives M. D. Coburn, B. W. Harris, H. H. Hayden, K. Y. Lee and M. M. Stinecipher,Ind. Eng. Chem. ...
References 291 R. J. Spear and W. S. Wilson,J. Energ. Mater., 1984, 2 , 61. I. J. Dagley and R. J. Spear, inOrganic Energetic C ...
292 ...
7 Energetic Compounds 3: N-Heterocycles 7.1 Introduction Until the end of the First World War the main filling for mass ordnance ...
294 N-Heterocycles easy to synthesize and, coupled with their high performance, it is probable that some of these compounds may ...
5-Membered rings – 2N 295 NOH 2 NN N H NO CH 3 H 3 CH 3 C N H NH 2 CH 3 N N H N 2 CH 3 H 3 C N H N H N N CH 3 N H N H N N O 2 N ...
296 N-Heterocycles Poullain and co-workers^10 synthesized N-substituted-3,5-diamino-4-nitropyrazoles by treating substituted pyr ...
5-Membered rings – 2N 297 alternative to TNT for mass use in ordnance. At present, chemists at Lawrence Livermore National Labor ...
298 N-Heterocycles nitro-substituted furazans have excellent oxygen balance and exhibit detonation velocities close to very powe ...
5-Membered rings – 2N 299 4-amino-4′-nitro-3,3′-azofurazan (29).^25 The use of stronger hydrogen peroxide solutions can oxidize ...
300 N-Heterocycles Coburn^17 synthesized 3-nitro-4-(picrylamino)furazan (37) from the reaction of DAF (24) with one equivalent o ...
5-Membered rings – 2N 301 N O N H 2 N N H H N N H H N N O N N O N NO 2 NO 2 NO 2 NO 2 OO HH + HCl (aq) TFAA, HNO 3 45 N N N N N ...
302 N-Heterocycles dioxide in acetonitrile. The bis-nitramine (53) is too reactive for practical use, although the bis-picryl de ...
5-Membered rings – 2N 303 NN O CON 3 N OO N 3 OC N Na 2 WO 4 dioxane (aq), 80 °C KMnO 4 , HCl (aq) acetone 90 % H 2 O 2 , H 2 SO ...
304 N-Heterocycles Cl O 2 N NO 2 NO 2 67 N 3 O 2 N NO 2 NO 2 70 NaN 3 N O N O N O N O NO 2 O 2 N NH 2 OH, NaOEt H 2 SO 4 , HNO 3 ...
5-Membered rings – 2N 305 7-amino-4,6-dinitrobenzofuroxan (77) (ADNBF) is more impact insensitive than 4,6- dinitrobenzofuroxan. ...
306 N-Heterocycles N H N H N NO 2 O 2 N O 2 N NO 2 N O N N O N NO N O N H N H N NO 2 N N N OO O O N N O N NO N O O O NH O 2 N O ...
5-Membered rings – 3N 307 The tetraazapentalene ring system forms the core of the thermally insensitive explosive TACOT (Section ...
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