Organic Chemistry of Explosives

248 Synthetic Routes toN-Nitro higher performance of HMX compared to RDX is offset by its higher cost of production. Conse- quen ...

The nitrolysis of hexamine 249 DPT (239) with a mixture of acetic anhydride, ammonium nitrate and nitric acid at 65–70◦C furnish ...

250 Synthetic Routes toN-Nitro O 2 N NO 2 99 % HNO 3 96 % H 2 SO 4 98 % HNO 3 , 88 % PPA, 60 °C or 98 % HNO 3 , P 2 O 5 , 50 °C ...

The nitrolysis of hexamine 251 of hexamine nitrolysis and the distribution of products obtained. Variations in such conditions h ...

252 Synthetic Routes toN-Nitro 5.15.3.2 Effect of acidity and the presence of ammonium nitrate on the nitrolysis of hexamine Bac ...

The nitrolysis of hexamine 253 CH 2 N NN N H 2 C CH 2 H 2 C CH 2 O 2 N NO 2 NO 2 4 (HMX) N NN N H 2 C CH 2 H 2 C CH 2 O 2 N NO 2 ...

254 Synthetic Routes toN-Nitro CH 2 N NN N H 2 C CH 2 H 2 C CH 2 O 2 N NO 2 HO OH NO 2 252 N NN N H 2 C CH 2 H 2 C CH 2 O 2 N NO ...

References 255 of fuming nitric acid in acetic anhydride leads to the isolation of (247) (BSX), whereas the addition of 97 % nit ...

256 Synthetic Routes toN-Nitro Propellants, Pyrotechnics and Processing of Explosives, Propellants and Ingredients, San Diego, C ...

References 257 Methods Enzymol., 1972,25B, 515; (d) A. Castonguay and H. Van Vunakis,Toxicol. Lett., 1979, 4 , 475. C. M. Adams ...

258 Synthetic Routes toN-Nitro (a) A. T. Nielsen,US Pat. 253 106 (1988);Chem. Abstr., 1998, 128 , 36971t; (b) A. T. Nielsen, ‘S ...

References 259 P. Golding, R. W. Millar, N. C. Paul and D. H. Richards,Tetrahedron, 1993, 49 , 7063. P. Golding, R. W. Millar, ...

260 Synthetic Routes toN-Nitro J. A. Bell and I. Dunstan,J. Chem. Soc. (C), 1966, 862. J. A. Bell and I. Dunstan,J. Chem. Soc. ...

References 261 G. F. Henning,Ger. Pat. 104 280 (1899). E. V. Herz,Brit. Pat. 145 791 (1920);US Pat. 1 402 693 (1922). G. C. Hal ...

262 ...

6 Energetic Compounds 2: Nitramines and Their Derivatives In Chapter 5 we discussed the methods used to incorporateN-nitro funct ...

264 Nitramines and Their Derivatives 6.2 Cyclobutanes H 2 N OEt OEt H 2 N H O OEt OEt NHHN O AcN NAc O AcN NAc AcN NAc O O 7 HN ...

Azetidines – 1,3,3-trinitroazetidine 265 paraformaldehyde in 80 % aqueous sulfuric acid yields octahydro-1,3,4,6-tetranitro-3a,3 ...

266 Nitramines and Their Derivatives Archibald and co-workers^4 reported the first synthesis of TNAZ (18) in 1989. This route us ...

Azetidines – 1,3,3-trinitroazetidine 267 Br Br NH 3 Br 25 N 26 N NO 27 NaOH (aq), 80 °C H remove via azeotropic distillation NaN ...