Organic Chemistry of Explosives
208 Synthetic Routes toN-Nitro acetic anhydride during the nitration of alkyldichloramines is essential in keeping the reaction ...
N-Nitration of amides and related compounds 209 of 70 % PETN and 30 %N, N′-dinitro-N, N′-dimethyloxamide melts at 100◦C and has ...
210 Synthetic Routes toN-Nitro O O NCH 2 CH 2 ONO 2 NCH 2 CH 2 ONO 2 NO 2 NO 2 11 (NENO) O O NCH 2 CH 2 OH NCH 2 CH 2 OH NO 2 NO ...
N-Nitration of amides and related compounds 211 N NN N O O 2 N O 2 N NO 2 69 NO^2 (TNGU) N NN N O 14 NO^2 (DINGU) N H H N H N N ...
212 Synthetic Routes toN-Nitro 5.5.2.1 Dinitrogen pentoxide Von Runge and Triebs^81 used a solution of dinitrogen pentoxide in c ...
Nitrolysis 213 and Suri^89 used the same system, which probably involves trifluoroacetyl nitrate as the active nitrating agent, ...
214 Synthetic Routes toN-Nitro the breakage of the amide bond in path A, whereas rupture of either of the other two C–N bonds in ...
Nitrolysis 215 CH 3 CO C 2 H 5 CO n-C 3 H 7 CO (CH 3 ) 2 CHCO (CH 3 ) 3 CCO CH 3 OCO t-BuOCO N N RR R N N O 2 N NO 2 NO 2 R (see ...
216 Synthetic Routes toN-Nitro The high performance nitramine explosive known as CL-20 (5) has been synthesized via a two-stage ...
Nitrolysis 217 N, N′-Diacetylimidazolidine (87) undergoes nitrolysis on treatment with nitronium tetrafluo- roborate to yield ei ...
218 Synthetic Routes toN-Nitro anhydride–nitric acid mixtures.^107 In these reactions, ring nitration to 2,4-dinitro-N, N- dimet ...
Nitrolysis 219 from this study were found to be powerful explosives. Adolph and Cichra^108 found that the hydrochloride salt oft ...
220 Synthetic Routes toN-Nitro 5.6.2.3 Methylenediamines Methylenediamines are readily synthesized from the reaction of secondar ...
Nitrolysis 221 The nitrolysis of (107) with nitric acid–trifluoroacetic anhydride yields 2,4,6-trinitro-2,4,6- triazaheptane (10 ...
222 Synthetic Routes toN-Nitro H 2 N(CH 2 ) 2 NH 2 H 2 N(CH 2 ) 3 NH 2 C(CH 2 NH 2 ) 4 NN NOON NN O 2 N NO 2 ON NO O 2 NN NNO 2 ...
Nitrative cleavage of other nitrogen bonds 223 N N N CF 3 NOON NO F 3 C CF 3 N N N CF 3 O 2 N NO 2 NO 2 F 3 C CF 3 HNO 3 , TFAA ...
224 Synthetic Routes toN-Nitro bond has been reported in the form of HMPA, which forms dimethylnitramine on reaction with nitric ...
Ring-opening nitration of nitrogen heterocycles 225 Good yields are attainable for some sterically hindered nitramines like di-i ...
226 Synthetic Routes toN-Nitro Millar and co-workers124–126studied the ring-opening nitration of strained nitrogen hetero- cycle ...
Ring-opening nitration of nitrogen heterocycles 227 compounds, known as NENAs, find use as energetic plasticizers; then-butyl an ...
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