Concise Physical Chemistry

c03 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come 54 THE THERMODYNAMICS OF SIMPLE SYSTEMS Problem 3.5 In a J ...

c03 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come PROBLEMS AND EXAMPLE 55 Problem 3.12 The ratioγ=Cp/CVis 1. ...

c04 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come 4 THERMOCHEMISTRY Einstein once said, “Some things are sim ...

c04 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come ENERGIES AND ENTHALPIES OF FORMATION 57 we still measure t ...

c04 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come 58 THERMOCHEMISTRY
H=
U+
nRTunder the ideal gas assumptio ...

c04 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come MOLECULAR ENTHALPIES OF FORMATION 59 -393.5 -283.0 FIGURE ...

c04 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come 60 THERMOCHEMISTRY 2(286)=572 394 -890 -76 methane element ...

c04 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come ENTHALPIES OF REACTION 61 under all known experimental con ...

c04 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come 62 THERMOCHEMISTRY database with a variety of entries (web ...

c04 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come GROUP ADDITIVITY 63 If we were asked to predict
cH^298 (n- ...

c04 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come 64 THERMOCHEMISTRY 4.7
fH^298 (g)FROM CLASSICAL MECHANICS ...

c04 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come VA R I AT I O N O F
HWITHT 65 Hence the bond energy is the ...

c04 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come 66 THERMOCHEMISTRY The change in
rHfor relatively small ch ...

c04 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come DIFFERENTIAL SCANNING CALORIMETRY 67 and it will be little ...

c04 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come 68 THERMOCHEMISTRY The heat capacity curve of the simple s ...

c04 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come PROBLEMS AND EXAMPLE 69 Problem 4.3 The enthalpy of format ...

c04 JWBS043-Rogers September 13, 2010 11:24 Printer Name: Yet to Come 70 THERMOCHEMISTRY Problem 4.8 Plot the heat capacity of e ...

c05 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 5 Entropy and the Second Law The second law of thermodynam ...

c05 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 72 ENTROPY AND THE SECOND LAW HOT COLD WORK FIGURE 5.1 An ...

c05 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come ENTROPY 73 but restoring the system entropy to its origina ...