Concise Physical Chemistry

c05 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 74 ENTROPY AND THE SECOND LAW but this is not the case. Th ...

c05 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come ENTROPY CHANGES 75 Hence dSrev≡ dqrev T = dH T =Cp dT T Ta ...

c05 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 76 ENTROPY AND THE SECOND LAW We know from the second law ...

c05 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come SPONTANEOUS PROCESSES 77 These derivations are given in mo ...

c05 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 78 ENTROPY AND THE SECOND LAW by the cold one. The process ...

c05 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come THE THIRD LAW 79 Because of the third law, it is possible ...

c05 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 80 ENTROPY AND THE SECOND LAW involving the energy and the ...

c05 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come PROBLEMS AND EXAMPLE 81 Cp/ T vs. T Silver(s) T,K 0 50 100 ...

c05 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 82 ENTROPY AND THE SECOND LAW Problem 5.3 What is the entr ...

c05 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come PROBLEMS AND EXAMPLE 83 Problem 5.8 TheCp/Tvs.Tdata set fo ...

c06 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 6 The Gibbs Free Energy Our brief consideration of engines ...

c06 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come FREE ENERGIES OF FORMATION 85 This equation implies consta ...

c06 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 86 THE GIBBS FREE ENERGY to get
Sr^298 = 213. 74 − 5. 74 ...

c06 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come PRESSURE DEPENDENCE OF THE CHEMICAL POTENTIAL 87 6.4 THE F ...

c06 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 88 THE GIBBS FREE ENERGY 4 2 2 2 3 1 1 bar 1 bar (, ) (, ) ...

c06 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come THE TEMPERATURE DEPENDENCE OF THE FREE ENERGY 89 where we ...

c06 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 90 THE GIBBS FREE ENERGY PROBLEMS AND EXAMPLE Example 6.1 ...

c06 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come PROBLEMS AND EXAMPLE 91 (c) Show thatdU=TdS−pdV. (d) Combi ...

c06 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 92 THE GIBBS FREE ENERGY TCp 15.0000 6.9000 20.0000 12.000 ...

c07 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 7 Equilibrium Chemists are often depicted in the popular m ...