Concise Physical Chemistry

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 114 A STATISTICAL APPROACH TO THERMODYNAMICS TABLE 8.1 The ...

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come THE PARTITION FUNCTION OF A SIMPLE SYSTEM 115 equally spac ...

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 116 A STATISTICAL APPROACH TO THERMODYNAMICS Similarly, th ...

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come THE EQUILIBRIUM CONSTANT: A STATISTICAL APPROACH 117 This ...

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 118 A STATISTICAL APPROACH TO THERMODYNAMICS allowed. Now, ...

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come COMPUTATIONAL STATISTICAL THERMODYNAMICS 119 The thermal w ...

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 120 A STATISTICAL APPROACH TO THERMODYNAMICS TABLE 8.2 Som ...

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come PROBLEMS AND EXAMPLES 121 For Na 2 (g) molecules, a simila ...

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 122 A STATISTICAL APPROACH TO THERMODYNAMICS When these tw ...

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come PROBLEMS AND EXAMPLES 123 Problem 8.6 Given that Qtr= ( 2 ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come 9 The Phase Rule It is essential in science for experiment ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come COEXISTENCE CURVES 125 system ice and water has one compon ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come 126 THE PHASE RULE H 2 O(gas) H 2 O(liquid) H 2 O(gas) FIG ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come COEXISTENCE CURVES 127 p T T* p* FIGURE 9.2 A liquid–vapor ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come 128 THE PHASE RULE p T . vapor liquid solid FIGURE 9.3 A s ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come PARTIAL MOLAR VOLUME 129 we get lnp=
vapH R ( − 1 T ) +co ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come 130 THE PHASE RULE 0 1 X 2 Vm1 Vm2 V FIGURE 9.4 Total volu ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come PARTIAL MOLAR VOLUME 131 V n 2 FIGURE 9.6 Partial molar vo ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come 132 THE PHASE RULE The definition ofVm 2 should come as no ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come PARTIAL MOLAR VOLUME 133 quantities analogous to the parti ...