chemistry1

152 Synthetic Routes to AromaticC-Nitro Compounds protection as theirN-acetyl orN,N′-diacetyl derivatives. Thus, pentanitrotolue ...

Oxidation of arylamines, arylhydroxylamines and other derivatives 153 Table 4.2 Oxidation of arylamines with peroxycarboxylic ac ...

154 Synthetic Routes to AromaticC-Nitro Compounds Azo and azoxy compounds are potential by-products of peroxyacetic acid oxidati ...

Oxidation of arylamines, arylhydroxylamines and other derivatives 155 Dimethyldioxirane is a powerful oxidant prepared as a solu ...

156 Synthetic Routes to AromaticC-Nitro Compounds Table 4.3 Oxidation of arylhydroxylamines with ozone (ref. 39) NHOMe NO 2 NHOH ...

Nucleophilic aromatic substitution 157 fromN-hydroxy-2,4,6-trinitroaniline. The synthesis of 1,2,4,5-trinitrobenzene from the ni ...

158 Synthetic Routes to AromaticC-Nitro Compounds 4.8.1 Displacement of halide 4.8.1.1 Substrate reactivity X (NO 2 )n X = I, Br ...

Nucleophilic aromatic substitution 159 Cl NO 2 NO 2 N NO 2 NO 2 O 2 N O 2 N O 2 N O 2 N R R' OH NO 2 NO 2 NH 2 NO 2 NO 2 O 2 N O ...

160 Synthetic Routes to AromaticC-Nitro Compounds 2,2′,4,4′,6,6′-Hexanitroazobenzene (HNAB) (90), an explosive exhibiting therma ...

64 Synthetic Routes to AliphaticC-Nitro L. T. Eremenko and F. Ya. Natsibullin,Izv. Akad. Nauk USSR, Ser. Khim., 1969, 1331; Eng ...

Nucleophilic aromatic substitution 161 Picryl chloride (87) reacts with hydroxylamine hydrochloride to yield 2,4,6-trinitroanili ...

162 Synthetic Routes to AromaticC-Nitro Compounds which is synthesized from the reaction of 2,4-dinitrochlorobenzene (95) with a ...

Nucleophilic aromatic substitution 163 NO 2 O 2 N Cl 103 Cl NO 2 NO 2 95 N + N Figure 4.39 2,4-Dinitrochlorobenzene (95) reacts ...

164 Synthetic Routes to AromaticC-Nitro Compounds also increases crystal density and improves explosive performance.^236 Much re ...

Nucleophilic aromatic substitution 165 NH CH 3 NO 2 NO 2 NO 2 NO 2 O 2 N O 2 NO 2 2 NNO NO 2 NO 2 Cl CH 3 NH 2 107 (PADNT) + 85 ...

166 Synthetic Routes to AromaticC-Nitro Compounds 2,4,6-Tris(picrylamino)-1,3,5-trinitrobenzene (113), the product from condensi ...

Nucleophilic aromatic substitution 167 N N N NHHN NH O 2 N NO 2 NO 2 NO 2 NO 2 O 2 N NO 2 NO 2 H 2 N O 2 N NH 2 NH 2 NH 2 H 2 N ...

168 Synthetic Routes to AromaticC-Nitro Compounds Highly nitrated derivatives of benzene readily react with water to form phenol ...

Nucleophilic aromatic substitution 169 o/p-positions to one another, making them considerably more reactive towards nucleophilic ...

170 Synthetic Routes to AromaticC-Nitro Compounds CH 3 NO 2 NO 2 1 O 2 N CH 3 NO 2 NO 2 130 (DATNT) O 2 N H 2 N NH 2 N N NNH 2 D ...