chemistry1

Adamantanes 79 The search for energetic compounds with high crystal densities has focused attention on the polynitro derivatives ...

80 Polynitropolycycloalkanes Br Br Br Br AcHN AcHN NHAc NHAc Cl H 3 N Cl H 3 N NH 3 Cl NH 3 Cl O 2 N O 2 N NO 2 NO 2 (^100101) 1 ...

Adamantanes 81 NOH HON O Br O 2 N O 2 N O 2 N O 2 N NO 2 NO 2 NO 2 NO 2 NO 2 109, 68 % NO 2 108, 20 % Br H H + 105 NBS, NaHCO 3 ...

82 Polynitropolycycloalkanes Dave and co-workers^33 have reported a successful synthesis of 2,2,4,4-tetranitroadamantane (117) w ...

References 57 J. M. Birchall, A. J. Bloom, R. N. Haszeldine and C. J. Willis,J. Chem. Soc., 1962, 3021. (a) H. Petri,Z. Anorg. ...

Polynitrobicycloalkanes 83 NO 2 O 2 N O 2 N HCO OCH O O H H O O NOH HON HCOOH CrO 3 127 126 122 123 124 125 85 % Me 2 CO, 50 % N ...

84 Polynitropolycycloalkanes OMeMeO O OMeMeO NOH OMeMeO NO 2 NO 2 NO 2 NO 2 H OMeMeO NO 2 Br OMeMeO NO 2 NO 2 NO 2 NO 2 O NO 2 N ...

References 85 Olah and co-workers^36 reported the synthesis of 3,3,7,7-tetranitro-cis-bicyclo[3.3.0]octane (139) from the diketo ...

86 Polynitropolycycloalkanes (a) P. E. Eaton, R. Gilardi and M. -X. Zhang,Angew. Chem. Int. Ed., 2000, 39 , 401; (b) P. E. Eato ...

3 Synthetic Routes to Nitrate Esters This chapter discusses the various synthetic methods available for the synthesis and incorp ...

88 Synthetic Routes to Nitrate Esters of nitroglycerine has been reported for composite modified double-base (CMDB) propellants ...

Nitrate esters as explosives 89 The main aim of synthesis and characterization of these nitrate esters was to explore their use ...

90 Synthetic Routes to Nitrate Esters 3.2 Nitration of the parent alcohol 3.2.1O-Nitration with nitric acid and its mixtures The ...

Nitration of the parent alcohol 91 including: remote handling, elaborate reactors and blast-proof buildings. Product separation ...

92 Synthetic Routes to Nitrate Esters the nitrating agent of choice. Solid polyols like pentaerythritol, erythritol and mannitol ...

Nitration of the parent alcohol 93 treatment with reagents like mixed acid, nitric acid in chloroform, and 98 % nitric acid in a ...

58 Synthetic Routes to AliphaticC-Nitro R. K. Blackwood, G. E. Graham, N. Kornblum, H. O. Larson, D. D. Mooberry and E. P. Oliv ...

94 Synthetic Routes to Nitrate Esters N 2 O 5 , CCl 4 , 0 °C 98–100 % HO OH OH OH OH OH (^1314) O 2 NO ONO 2 ONO 2 ONO 2 ONO 2 O ...

Nitration of the parent alcohol 95 Commercially available nitronium tetrafluoroborate contains between 5 and 15 % nitroso- nium ...

96 Synthetic Routes to Nitrate Esters 3.2.6 OtherO-nitrating agents 3.2.6.1 Boron trifluoride hydrate–potassium nitrate Olah and ...