chemistry1

Nucleophilic displacement with nitrate anion 97 presence of secondary hydroxy groups. This is illustrated in the case of glycero ...

98 Synthetic Routes to Nitrate Esters give excellent yields of the corresponding nitrate ester. Allylic, benzylic and tertiary c ...

References 59 (a) D. A. Isacescu and C. D. Nenitzescu,Chem. Ber., 1930, 63 , 2484; (b) C. D. Nenitzescu,Chem. Ber., 1929, 62 , ...

Nitrate esters from strained oxygen heterocycles 99 of nitrate esters from carbohydrates. In these reactions the intermediate tr ...

60 Synthetic Routes to AliphaticC-Nitro L. A. Paquette, C. -C. Shen and L. M. Waykole,J. Org. Chem., 1988, 53 , 4969. P. Cecche ...

100 Synthetic Routes to Nitrate Esters 3.4.1.2 Vicinal dinitrate esters from the reaction of epoxides with dinitrogen pentoxide ...

Nitrate esters from strained oxygen heterocycles 101 co-workers^75 found it necessary to add aluminium chloride to the reaction ...

102 Synthetic Routes to Nitrate Esters Ceric ammonium nitrate (CAN) has been used for the synthesis ofβ-hydroxy nitrate esters f ...

Nitrodesilylation 103 as the sole product (62 %), whereas longer reaction times with 4.0 equivalents of dinitrogen pentoxide yie ...

104 Synthetic Routes to Nitrate Esters Trimethylsilyl ethers and other simplen-alkylsilyl ethers give high yields of nitrate est ...

Additions to alkenes 105 3.6.2 Nitrogen oxides N 2 O 4 , O 2 51 + + R R R R C R R R R O 2 N Et 2 O, 0 °C C NO 2 52 C R R R R O 2 ...

106 Synthetic Routes to Nitrate Esters Canfield and Rohrback^106 reported on the reaction of some electron-deficient difluo- roa ...

Miscellaneous methods 107 R NH 2 R ONO 2 -15 °C to -10 °C CH 3 CN, NO 2 F R = alkyl, FC(NO 2 ) 2 CH 2 , FC(NO 2 ) 2 CH 2 CH 2 Fi ...

108 Synthetic Routes to Nitrate Esters 3.9 Synthetic routes to some polyols and their nitrate ester derivatives CH 3 NO 2 + 3 CH ...

Synthetic routes to polyols and derivatives 109 on nitration with mixed acid. Metriol trinitrate (MTN) is a practical explosive ...

110 Synthetic Routes to Nitrate Esters C C CH 2 OH O 2 NOCH 2 CH 2 ONO 2 CH 2 OH CH 2 OH C CH 2 ONO 2 CH 2 ONO 2 CH 2 ONO 2 CH 2 ...

Synthetic routes to polyols and derivatives 111 C CH 2 OH CH 2 OH AcOCH 2 CH 2 OH C CH 2 ONO 2 CH 2 ONO 2 AcOCH 2 CH 2 ONO 2 C C ...

112 Synthetic Routes to Nitrate Esters C CH 2 ONO 2 CH 3 CH 2 ONO 2 C CH 2 OH CH 2 ONO 2 CH 3 CH 2 ONO 2 CH 2 OAcC CH 2 OH CH 3 ...

Energetic nitrate esters 113 O CH 2 N 3 CH 2 N 3 HOCH 2 CH 2 N 3 CH 2 N 3 O 2 NOCH 2 CCH 2 ONO 2 CH 2 N 3 CH 2 N 3 N 3 CH 2 CH 2 ...

114 Synthetic Routes to Nitrate Esters A number of secondary high explosives containing both nitramine and nitrate ester func- t ...