Physical Chemistry Third Edition

922 22 Translational, Rotational, and Vibrational States of Atoms and Molecules Exercise 22.2 Find the frequency and wavelength ...

22.2 The Nonelectronic States of Diatomic Molecules 923 so that Eq. (22.2-23) becomes h ̄^2 2 μ ( rd^2 S dr^2 − J(J+ 1 )rS r^2 ) ...

924 22 Translational, Rotational, and Vibrational States of Atoms and Molecules The wave function for the relative motion of the ...

22.2 The Nonelectronic States of Diatomic Molecules 925 The electronic energyEelfor the electronic ground state is usually assig ...

926 22 Translational, Rotational, and Vibrational States of Atoms and Molecules potential energy can be used.^1 The most commonl ...

22.2 The Nonelectronic States of Diatomic Molecules 927 The term containing the parameterDcauses the corrected levels to be more ...

928 22 Translational, Rotational, and Vibrational States of Atoms and Molecules The terms are commonly given in reciprocal centi ...

22.2 The Nonelectronic States of Diatomic Molecules 929 c. 1 λ  ∆E hc  E 11 hc − E 00 hc  ̃νe− 2 ̃Be  2169 .8cm−^1 +2(1.931 ...

930 22 Translational, Rotational, and Vibrational States of Atoms and Molecules 22.16a. From the vibrational frequency in Table ...

22.3 Nuclear Spins and Wave Function Symmetry 931 a multielectron atom can have different electronic spin states. Very large ene ...

932 22 Translational, Rotational, and Vibrational States of Atoms and Molecules eigenvalue+1 (are “gerade”), and for odd values ...

22.4 The Rotation and Vibration of Polyatomic Molecules 933 PROBLEMS Section 22.3: Nuclear Spins and Wave Function Symmetry 22.1 ...

934 22 Translational, Rotational, and Vibrational States of Atoms and Molecules The other products of inertia,Iyz,Izy,Ixz, andIz ...

22.4 The Rotation and Vibration of Polyatomic Molecules 935 Exercise 22.7 Show that the methane molecule is a spherical top. Sin ...

936 22 Translational, Rotational, and Vibrational States of Atoms and Molecules If the molecule is not oriented on thezaxis, the ...

22.4 The Rotation and Vibration of Polyatomic Molecules 937 symmetry number of BF 3 is 6 (three positions with one side of the m ...

938 22 Translational, Rotational, and Vibrational States of Atoms and Molecules depend on only 3n−5 of the new coordinates for a ...

22.4 The Rotation and Vibration of Polyatomic Molecules 939 Symmetric stretch n~ 15 1340 cm^21 Symmetric stretch n~ 15 1151.2 cm ...

940 22 Translational, Rotational, and Vibrational States of Atoms and Molecules PROBLEMS Section 22.4: The Rotation and Vibratio ...

22.4 The Rotation and Vibration of Polyatomic Molecules 941 torsional vibration relative to each other (this is called internal ...