Physical Chemistry Third Edition

1062 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States The probability distribution of ...

25.3 The Probability Distribution and the Molecular Partition Function 1063 Exercise 25.16 Verify Eq. (25.3-26) by evaluatingdβ/ ...

1064 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States 25.16The value of the molecular ...

25.4 The Calculation of Molecular Partition Functions 1065 EXAMPLE25.6 For the case thatg 0 1,ε 0 0 andε 1  1 .00 eV, show th ...

1066 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States v 52 Born–Oppenheimer energy v 5 ...

25.4 The Calculation of Molecular Partition Functions 1067 or by the parameterB ̃e, equal toBe/cwherecis the speed of light. The ...

1068 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States The formula given in Eq. (25.4-1 ...

25.4 The Calculation of Molecular Partition Functions 1069 The value in Example 25.7 is typical for molecules of moderate size n ...

1070 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States The excited vibrational states a ...

25.4 The Calculation of Molecular Partition Functions 1071 partition function. If additional electronic terms must be included, ...

1072 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States zrot 8 π^2 kBT h^2  kBT hBe  ...

25.4 The Calculation of Molecular Partition Functions 1073 the same formula as for atoms and diatomic molecules, Eq. (25.3-21). ...

1074 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States The Vibrational Partition Functi ...

25.4 The Calculation of Molecular Partition Functions 1075 Exercise 25.20 Calculate the vibrational partition function of sulfur ...

1076 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States for a volume of 1.00 m^3 at the ...

25.4 The Calculation of Molecular Partition Functions 1077 Summary of the Chapter The properties of macroscopic systems are dete ...

1078 25 Equilibrium Statistical Mechanics. I. The Probability Distribution for Molecular States d.What approximately is the effe ...

25.4 The Calculation of Molecular Partition Functions 1079 and so on. Repeat the calculation including states up to and includin ...

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26 Equilibrium Statistical Mechanics. II. Statistical Thermodynamics PRINCIPAL FACTS AND IDEAS Equilibrium thermodynamic variab ...