Physical Chemistry Third Edition

1102 26 Equilibrium Statistical Mechanics. II. Statistical Thermodynamics version of Eq. (26.3-5) for each substance is substitu ...

26.3 Chemical Equilibrium in Dilute Gases 1103 or Ke−∆ε^0 /kBT ∏s a 1 ( z′◦a NAv )νa (26.3-15) wherez′◦az′′aVm◦is the molecul ...

1104 26 Equilibrium Statistical Mechanics. II. Statistical Thermodynamics approximately equal to 1.000. The translational partit ...

26.3 Chemical Equilibrium in Dilute Gases 1105 wherec◦is defined to equal to 1 mol m−^3. Equation (26.3-9) can be written 0  ∆ε ...

1106 26 Equilibrium Statistical Mechanics. II. Statistical Thermodynamics vibrational partition functions≈1. Do your equilibrium ...

26.4 The Activated Complex Theory of Bimolecular Chemical Reaction Rates in Dilute Gases 1107 temperature, but is independent of ...

1108 26 Equilibrium Statistical Mechanics. II. Statistical Thermodynamics Energy of activated complex Activated complex Reaction ...

26.4 The Activated Complex Theory of Bimolecular Chemical Reaction Rates in Dilute Gases 1109 pass over the saddle and the time ...

1110 26 Equilibrium Statistical Mechanics. II. Statistical Thermodynamics motion along the reaction coordinate and leads to diss ...

26.4 The Activated Complex Theory of Bimolecular Chemical Reaction Rates in Dilute Gases 1111 and the rate constant is given by ...

1112 26 Equilibrium Statistical Mechanics. II. Statistical Thermodynamics  ( 2 π(1. 674 × 10 −^27 kg)(1. 3807 × 10 −^23 JK−^1 ) ...

26.4 The Activated Complex Theory of Bimolecular Chemical Reaction Rates in Dilute Gases 1113 z‡rot,HHBr′′  8 π^2 IekBT h^2  8 ...

1114 26 Equilibrium Statistical Mechanics. II. Statistical Thermodynamics where the equilibrium constantK ‡ cand the standard-st ...

26.4 The Activated Complex Theory of Bimolecular Chemical Reaction Rates in Dilute Gases 1115 EXAMPLE26.13 The experimental valu ...

1116 26 Equilibrium Statistical Mechanics. II. Statistical Thermodynamics calculated with the London–Eyring–Polanyi–Sato (LEPS) ...

26.5 Miscellaneous Topics in Statistical Thermodynamics 1117 These equations let us interpret the chemical potential as a kind o ...

1118 26 Equilibrium Statistical Mechanics. II. Statistical Thermodynamics From Eq. (25.2-17), we can write ∂ln(Wmp) ∂Ni −α+βεi ...

26.5 Miscellaneous Topics in Statistical Thermodynamics 1119 ADDITIONAL PROBLEMS 26.35 a.Find the value of the statistical entro ...

1120 26 Equilibrium Statistical Mechanics. II. Statistical Thermodynamics liquid hydrogen the molecules rotate freely. (This see ...

27 Equilibrium Statistical Mechanics. III. Ensembles PRINCIPAL FACTS AND IDEAS Statistical mechanics can be studied by visualiz ...