Science - USA (2022-04-29)
was also found to be amenable to a one-pot process, with initial formation of theN-oxide induced by hydrogen peroxide in dichlor ...
530 29 APRIL 2022¥VOL 376 ISSUE 6592 science.orgSCIENCE 2af, 47% [Hg Lamp: 0%] N Me Br O O Minisci alkylation then N H O O MeO C ...
2g, and2i), polyhalogenation (2v,2w, and 2x), carbamates (2y,2z,2aa, and2ab), phos- phonates (2o), sulfones (2s), and boronic es ...
substituent with a phenyl. Finally, if indole 5aois subjected to nitrogen insertion through a precedentedN-amination and oxidati ...
full potential because of their mechanistic ambiguity. In response to this challenge, we sought to develop an approach amenable ...
anilines, and phenols, led to attenuated reaction efficiency ( 41 ) (Fig. 2B). However, certain five-membered cyclic imides and ...
To gauge improvements in the functional group tolerance, compound X2 and cyclo- hexanoic acid were resubjected to the earlier ad ...
against the Aryl Halide Informer Library ( 42 ). This library is prototypical of the type of com- plex drug-like compounds seen ...
SCIENCEscience.org 29 APRIL 2022¥VOL 376 ISSUE 6592 537 Fig. 4. Mechanistic insight.(A) Decrease of protodehalogenation observed ...
overall rate of the reaction. We found that the addition of phthalimide led to an overall increase in the initial reaction rate, ...
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