Organic Chemistry of Explosives
148 Synthetic Routes to AromaticC-Nitro Compounds 4.6 Reaction of diazonium salts with nitrite anion Sandmeyer-type reactions ar ...
Oxidation of arylamines, arylhydroxylamines and other derivatives 149 1,2,4- and 1,2,3-trinitrobenzenes were formed from the iso ...
150 Synthetic Routes to AromaticC-Nitro Compounds Peroxydisulfuric acid (H 2 S 2 O 8 ) is one of the most powerful peroxyacid ox ...
Oxidation of arylamines, arylhydroxylamines and other derivatives 151 Table 4.1 Oxidation of arylamines and their derivatives wi ...
152 Synthetic Routes to AromaticC-Nitro Compounds protection as theirN-acetyl orN,N′-diacetyl derivatives. Thus, pentanitrotolue ...
Oxidation of arylamines, arylhydroxylamines and other derivatives 153 Table 4.2 Oxidation of arylamines with peroxycarboxylic ac ...
154 Synthetic Routes to AromaticC-Nitro Compounds Azo and azoxy compounds are potential by-products of peroxyacetic acid oxidati ...
Oxidation of arylamines, arylhydroxylamines and other derivatives 155 Dimethyldioxirane is a powerful oxidant prepared as a solu ...
156 Synthetic Routes to AromaticC-Nitro Compounds Table 4.3 Oxidation of arylhydroxylamines with ozone (ref. 39) NHOMe NO 2 NHOH ...
Nucleophilic aromatic substitution 157 fromN-hydroxy-2,4,6-trinitroaniline. The synthesis of 1,2,4,5-trinitrobenzene from the ni ...
158 Synthetic Routes to AromaticC-Nitro Compounds 4.8.1 Displacement of halide 4.8.1.1 Substrate reactivity X (NO 2 )n X = I, Br ...
Nucleophilic aromatic substitution 159 Cl NO 2 NO 2 N NO 2 NO 2 O 2 N O 2 N O 2 N O 2 N R R' OH NO 2 NO 2 NH 2 NO 2 NO 2 O 2 N O ...
160 Synthetic Routes to AromaticC-Nitro Compounds 2,2′,4,4′,6,6′-Hexanitroazobenzene (HNAB) (90), an explosive exhibiting therma ...
Nucleophilic aromatic substitution 161 Picryl chloride (87) reacts with hydroxylamine hydrochloride to yield 2,4,6-trinitroanili ...
162 Synthetic Routes to AromaticC-Nitro Compounds which is synthesized from the reaction of 2,4-dinitrochlorobenzene (95) with a ...
Nucleophilic aromatic substitution 163 NO 2 O 2 N Cl 103 Cl NO 2 NO 2 95 N + N Figure 4.39 2,4-Dinitrochlorobenzene (95) reacts ...
164 Synthetic Routes to AromaticC-Nitro Compounds also increases crystal density and improves explosive performance.^236 Much re ...
Nucleophilic aromatic substitution 165 NH CH 3 NO 2 NO 2 NO 2 NO 2 O 2 N O 2 NO 2 2 NNO NO 2 NO 2 Cl CH 3 NH 2 107 (PADNT) + 85 ...
166 Synthetic Routes to AromaticC-Nitro Compounds 2,4,6-Tris(picrylamino)-1,3,5-trinitrobenzene (113), the product from condensi ...
Nucleophilic aromatic substitution 167 N N N NHHN NH O 2 N NO 2 NO 2 NO 2 NO 2 O 2 N NO 2 NO 2 H 2 N O 2 N NH 2 NH 2 NH 2 H 2 N ...
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