Organic Chemistry of Explosives
88 Synthetic Routes to Nitrate Esters of nitroglycerine has been reported for composite modified double-base (CMDB) propellants ...
Nitrate esters as explosives 89 The main aim of synthesis and characterization of these nitrate esters was to explore their use ...
90 Synthetic Routes to Nitrate Esters 3.2 Nitration of the parent alcohol 3.2.1O-Nitration with nitric acid and its mixtures The ...
Nitration of the parent alcohol 91 including: remote handling, elaborate reactors and blast-proof buildings. Product separation ...
92 Synthetic Routes to Nitrate Esters the nitrating agent of choice. Solid polyols like pentaerythritol, erythritol and mannitol ...
Nitration of the parent alcohol 93 treatment with reagents like mixed acid, nitric acid in chloroform, and 98 % nitric acid in a ...
94 Synthetic Routes to Nitrate Esters N 2 O 5 , CCl 4 , 0 °C 98–100 % HO OH OH OH OH OH (^1314) O 2 NO ONO 2 ONO 2 ONO 2 ONO 2 O ...
Nitration of the parent alcohol 95 Commercially available nitronium tetrafluoroborate contains between 5 and 15 % nitroso- nium ...
96 Synthetic Routes to Nitrate Esters 3.2.6 OtherO-nitrating agents 3.2.6.1 Boron trifluoride hydrate–potassium nitrate Olah and ...
Nucleophilic displacement with nitrate anion 97 presence of secondary hydroxy groups. This is illustrated in the case of glycero ...
98 Synthetic Routes to Nitrate Esters give excellent yields of the corresponding nitrate ester. Allylic, benzylic and tertiary c ...
Nitrate esters from strained oxygen heterocycles 99 of nitrate esters from carbohydrates. In these reactions the intermediate tr ...
100 Synthetic Routes to Nitrate Esters 3.4.1.2 Vicinal dinitrate esters from the reaction of epoxides with dinitrogen pentoxide ...
Nitrate esters from strained oxygen heterocycles 101 co-workers^75 found it necessary to add aluminium chloride to the reaction ...
102 Synthetic Routes to Nitrate Esters Ceric ammonium nitrate (CAN) has been used for the synthesis ofβ-hydroxy nitrate esters f ...
Nitrodesilylation 103 as the sole product (62 %), whereas longer reaction times with 4.0 equivalents of dinitrogen pentoxide yie ...
104 Synthetic Routes to Nitrate Esters Trimethylsilyl ethers and other simplen-alkylsilyl ethers give high yields of nitrate est ...
Additions to alkenes 105 3.6.2 Nitrogen oxides N 2 O 4 , O 2 51 + + R R R R C R R R R O 2 N Et 2 O, 0 °C C NO 2 52 C R R R R O 2 ...
106 Synthetic Routes to Nitrate Esters Canfield and Rohrback^106 reported on the reaction of some electron-deficient difluo- roa ...
Miscellaneous methods 107 R NH 2 R ONO 2 -15 °C to -10 °C CH 3 CN, NO 2 F R = alkyl, FC(NO 2 ) 2 CH 2 , FC(NO 2 ) 2 CH 2 CH 2 Fi ...
«
2
3
4
5
6
7
8
9
10
11
»
Free download pdf