Organic Chemistry of Explosives
168 Synthetic Routes to AromaticC-Nitro Compounds Highly nitrated derivatives of benzene readily react with water to form phenol ...
Nucleophilic aromatic substitution 169 o/p-positions to one another, making them considerably more reactive towards nucleophilic ...
170 Synthetic Routes to AromaticC-Nitro Compounds CH 3 NO 2 NO 2 1 O 2 N CH 3 NO 2 NO 2 130 (DATNT) O 2 N H 2 N NH 2 N N NNH 2 D ...
Nucleophilic aromatic substitution 171 must not be used for the recrystallization of 2,4,6-trinitrophenetole and vice versa. The ...
172 Synthetic Routes to AromaticC-Nitro Compounds Warman and Siele^237 reported a high yielding route to 1,3-dichloro-2,4,6-trin ...
Nucleophilic aromatic substitution 173 The tri-nitration of 3,5-dichloroanisole (134) followed by ammonolysis of the product (13 ...
174 Synthetic Routes to AromaticC-Nitro Compounds NO 2 NO 2 53 O 2 N NH 2 VNS aminating agent (NH 2 OH, ATA, TMHI) DMSO, NaOMe N ...
The chemistry of 2,4,6-trinitrotoluene 175 under basic conditions and can attack an iminium cation formed from the reaction of f ...
176 Synthetic Routes to AromaticC-Nitro Compounds CH 2 Cl O 2 N NO 2 O 2 N O 2 N NO 2 O 2 N 145 CH CH NO 2 NO 2 NO 2 THF, MeOH, ...
Conjugation and thermally insensitive explosives 177 2,2′,4,4′,6,6′-Hexanitrostilbene (HNS, m.p. 316◦C,d= 1 .74 g/cm^3 ,VOD∼7000 ...
178 Synthetic Routes to AromaticC-Nitro Compounds COOH Cl 150 COOH Cl 151 O 2 N NO 2 NH 2 Cl 152 O 2 N NO 2 N Cl NO 2 NO 2 2 N N ...
Conjugation and thermally insensitive explosives 179 coupling of styphnyl chloride (106) with two equivalents of picryl chloride ...
180 Synthetic Routes to AromaticC-Nitro Compounds References G. A. Olah, R. Malhotra and S. C. Narang,Nitration: Methods and Me ...
References 181 Prep. Proc. Int., 1973, 5 , 271; (c) A. Gay-Lussac and J. Meniger,M ́em. Poudres, 1958, 40 ,7;Chem. Abstr., 1961, ...
182 Synthetic Routes to AromaticC-Nitro Compounds P. F. Frankland and F. H. Garner,Chem. Ind (London), 1920, 259. (a) N. Picton ...
References 183 J. W. Barnett, R. B. Moodie, K. Schofield, P. G. Taylor and J. B. Weston,J. Chem. Soc. Perkin Trans. I, 1979, 74 ...
184 Synthetic Routes to AromaticC-Nitro Compounds Tetrahedron Lett, 1991, 32 , 6591; (d) K. Maeda, T. Mori, H. Suzuki and S. Yon ...
References 185 (a) J. Glazer, E. D. Hughes, C. K. Ingold, A. T. James, G. T. Jones and E. Roberts,J. Chem. Soc., 1950, 2657; (b ...
186 Synthetic Routes to AromaticC-Nitro Compounds E. Bamberger and T. Tschirner,Chem. Ber., 1898, 31 , 1522. J. H. Boyer, inHet ...
References 187 (a) L. Desvergnes,M ́em. Poudres, 1918–22, 19 , 217, 269; 1931, 25 , 3, 291, 507, 1271; (b) L. Desvergnes,Chimie ...
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