Organic Chemistry of Explosives
68 Polynitropolycycloalkanes more of a science than a balancing act. Correlations between structure and properties such as therm ...
Cyclobutanes and their derivatives 69 where the two electronegative nitro groups are positionedanti-periplanar to one another. T ...
70 Polynitropolycycloalkanes Archibald and co-workers^5 found that aminocyclobutanes could be oxidized to the cor- responding ni ...
Cubanes 71 in alkaline solution.^5 No reference is made to the attempted oxidative nitration of (24) to 2,2,5,5,8,8,10,10-octani ...
72 Polynitropolycycloalkanes 1,4-Dinitrocubane (28) has been synthesized by Eaton and co-workers^6 ,^8 via two routes both start ...
Cubanes 73 respectively. Fractional recrystallization of this isomeric mixture from diethyl ether affords the 1,3,5,7-isomer (35 ...
74 Polynitropolycycloalkanes (2.028 g/cm^3 ) is higher than octanitrocubane, and so this compound, which is easier to synthe- si ...
Homocubanes 75 Marchand and co-workers^20 synthesis of 5,5,9,9-tetranitropentacyclo[5.3.0.0^2 ,^6 .0^3 ,^10 .0^4 ,^8 ] decane (5 ...
76 Polynitropolycycloalkanes Tests onD 3 -hexanitrotrishomocubane show it to be both less sensitive and significantly more power ...
Homocubanes 77 gem-dinitro group via the oxime (67). Deprotection of the acetal (70), followed by elaboration of the ketone func ...
78 Polynitropolycycloalkanes OH OH OH OH Br Br Br Br O O Br Br O O O O Br Br Br Br O OO O Br Br HOOC COOH COOH HOOC ClOC COCl Cl ...
Adamantanes 79 The search for energetic compounds with high crystal densities has focused attention on the polynitro derivatives ...
80 Polynitropolycycloalkanes Br Br Br Br AcHN AcHN NHAc NHAc Cl H 3 N Cl H 3 N NH 3 Cl NH 3 Cl O 2 N O 2 N NO 2 NO 2 (^100101) 1 ...
Adamantanes 81 NOH HON O Br O 2 N O 2 N O 2 N O 2 N NO 2 NO 2 NO 2 NO 2 NO 2 109, 68 % NO 2 108, 20 % Br H H + 105 NBS, NaHCO 3 ...
82 Polynitropolycycloalkanes Dave and co-workers^33 have reported a successful synthesis of 2,2,4,4-tetranitroadamantane (117) w ...
Polynitrobicycloalkanes 83 NO 2 O 2 N O 2 N HCO OCH O O H H O O NOH HON HCOOH CrO 3 127 126 122 123 124 125 85 % Me 2 CO, 50 % N ...
84 Polynitropolycycloalkanes OMeMeO O OMeMeO NOH OMeMeO NO 2 NO 2 NO 2 NO 2 H OMeMeO NO 2 Br OMeMeO NO 2 NO 2 NO 2 NO 2 O NO 2 N ...
References 85 Olah and co-workers^36 reported the synthesis of 3,3,7,7-tetranitro-cis-bicyclo[3.3.0]octane (139) from the diketo ...
86 Polynitropolycycloalkanes (a) P. E. Eaton, R. Gilardi and M. -X. Zhang,Angew. Chem. Int. Ed., 2000, 39 , 401; (b) P. E. Eato ...
3 Synthetic Routes to Nitrate Esters This chapter discusses the various synthetic methods available for the synthesis and incorp ...
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