Organic Chemistry of Explosives
JWBK121-FM October 11, 2006 21:10 Char Count= 0 xviii Abbreviations HMX 1,3,5,7-Tetranitro-1,3,5,7-tetraazacyclooctane HNAB 2,2′ ...
JWBK121-FM October 11, 2006 21:10 Char Count= 0 Abbreviations xix NIMMO 3-Nitratomethyl-3-methyloxetane NMHP 5-(Nitratomethyl)-1 ...
JWBK121-FM October 11, 2006 21:10 Char Count= 0 xx Abbreviations SDATO 1,3-Bis(1,2,4-triazol-3-amino)-2,4,6-trinitrobenzene (BTA ...
JWBK121-FM October 11, 2006 21:10 Char Count= 0 Abbreviations xxi Ts Tosyl or 4-toluenesulphonyl [4-MeC 6 H 4 SO 2 ] UDMH Unsymm ...
JWBK121-FM October 11, 2006 21:10 Char Count= 0 xxii ...
JWBK121-FM October 11, 2006 21:10 Char Count= 0 Acknowledgements While writing this book we have consulted innumerable research ...
JWBK121-FM October 11, 2006 21:10 Char Count= 0 xxiv Acknowledgements R. G. Coombes, “Nitro and Nitroso Compounds,” inComprehen ...
JWBK121-FM October 11, 2006 21:10 Char Count= 0 Background In the simplest terms, an explosive is defined as a substance, which ...
JWBK121-FM October 11, 2006 21:10 Char Count= 0 xxvi Background primary explosives are poor initiators while others are powerful ...
JWBK121-FM October 11, 2006 21:10 Char Count= 0 Background xxvii Most organic explosives contain nitrate ester, nitramine, or al ...
JWBK121-FM October 11, 2006 21:10 Char Count= 0 xxviii ...
JWBK121-FM October 11, 2006 21:10 Char Count= 0 Caution! Read This The information given in this book is believed to be accurate ...
JWBK121-FM October 11, 2006 21:10 Char Count= 0 xxx ...
1 Synthetic Routes to Aliphatic C-Nitro Functionality 1.1 Introduction The nitro group, whether attached to aromatic or aliphati ...
2 Synthetic Routes to AliphaticC-Nitro functionalized compounds, of which some find application as energetic plasticizers and po ...
Addition of nitric acid, nitrogen oxides 3 centres which are only nitrated with difficulty. With increased temperature these rea ...
4 Synthetic Routes to AliphaticC-Nitro The reaction of fuming nitric acid with 2-methyl-2-butene (3) is reported to yield 2-meth ...
Addition of nitric acid, nitrogen oxides 5 1,2-Dinitroethane and 1,2-dinitrocyclohexane can be formed in this way from the corre ...
6 Synthetic Routes to AliphaticC-Nitro At temperatures between 0◦C and 25◦C thevic-dinitrate ester is often observed in the prod ...
Halide displacement 7 treatment of the resultingβ-nitroalkyl bromide with triethylamine, is also a general route to α-nitroalken ...
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