Organic Chemistry of Explosives
28 Synthetic Routes to AliphaticC-Nitro Feuer and co-workers^209 conducted extensive studies into alkaline nitration with nitrat ...
Nitration of compounds containing acidic hydrogen 29 NCCH 2 (CH 2 ) 2 CH 2 CN O 2 NCH 2 (CH 2 ) 2 CH 2 NO 2 CCH 2 CH 2 C NO 2 CN ...
30 Synthetic Routes to AliphaticC-Nitro carbanions such as malonate arises from the perturbation of a side-reaction observed wit ...
Nitration of compounds containing acidic hydrogen 31 inductive effect of three nitro groups and the increased sp^2 character of ...
32 Synthetic Routes to AliphaticC-Nitro Trinitroacetonitrile (110), a precursor to dinitroacetonitrile and its derivatives, can ...
Addition and condensation reactions 33 1.10 ADDITION AND CONDENSATION REACTIONS Primary and secondary nitroalkanes, and substrat ...
34 Synthetic Routes to AliphaticC-Nitro the reaction of nitroform (112) with the corresponding vinyl ethers.^243 The synthesis o ...
Addition and condensation reactions 35 HC COEt NO 2 NO 2 119 Hg(OAc) 2 H 3 C OEt OCH 2 CF(NO 2 ) 2 OCH 2 CF(NO 2 ) 2 126 125 CH ...
36 Synthetic Routes to AliphaticC-Nitro H 2 C CHCO 2 Me NO 2 NO 2 127 O 2 N NO 2 NO 2 128 O 2 N HC(NO 2 ) 3 + Steps C CH 2 CH 2 ...
Addition and condensation reactions 37 +2 H 2 C CHY MeOH, NaOH C NO 2 NO 2 (CH 2 )n C NO 2 NO 2 NO 2 NO 2 YCH 2 CH 2 (CH 2 )n Y ...
38 Synthetic Routes to AliphaticC-Nitro alcohols with two or more strong electron-withdrawing groups on theβ-carbon atom to the ...
Addition and condensation reactions 39 Table 1.10 Michael 1,4-addition of nitroalkanes and nitramines with 2-nitroacetates (nitr ...
40 Synthetic Routes to AliphaticC-Nitro Frankel^258 synthesized 2-nitro-3-acetoxy-1-propene (139) by heating 1,3-diacetoxy-2- ni ...
Addition and condensation reactions 41 form the 1,1-dinitroethane anion (149) (Pathway 1). More unusual is the second reaction w ...
42 Synthetic Routes to AliphaticC-Nitro CCH 2 OAc NO 2 Br NO 2 CCH 2 OAc O 2 N KO 2 N NO 2 NO 2 H H NO 2 NO 2 H H H 2 SO 4 CCH 2 ...
Addition and condensation reactions 43 1.10.3 Mannich reaction R 2 NCH 2 + H 2 O (Eq. 1.4) R 2 NCH 2 C(NO 2 ) 3 (Eq. 1.5) R 2 NC ...
44 Synthetic Routes to AliphaticC-Nitro Frankel and Klager^289 have reported using the Mannich reaction for the condensation of ...
Addition and condensation reactions 45 Formaldehyde is the most important aldehyde used in Henry reactions in relation to ener- ...
46 Synthetic Routes to AliphaticC-Nitro derivatives are much safer to store than the parent nitronate salts and are readily conv ...
Derivatives of polynitroaliphatic alcohols 47 in the presence of TFAA or PPA as condensing agents;^310 ,^313 ,^314 (4)trans-este ...
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