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NITRO DERIVATIVES OF TOLUENE^329 Heat of nitration. Heats of direct conversion of dinitrotoluenes to trinitrotoluenes are listed ...

330 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES; in the meta position to the CH 3 group, is rather mobile as it is in the ortho or pa ...

NITRO DERIVATIVES OF TOLUENE^331 The unsymmetrical isomers of trinitrotoluene also give specific reactions with sodium carbonate ...

332 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES of amines (Brown and Campbell [142]). It has also been utilized for determining the s ...

NITRO DERIVATIVES OF TOLUENE 333 This is a nucleophilic reaction, and its mechanism, according to the author of the present book ...

334 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES Muraour observed the important fact that trinitro-m-xylene reacts with sodium sulphit ...

NITRO DERIVATIVES OF TOLUENE^335 permanent and transient solubility of a-trinitrotoluene in solutions of sodium sul- phite of di ...

336 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES Effect of light The unsymmetrical isomers of trinitrotoluene are affected by light in ...

NITRO DERIVATIVES OF TOLUENE 337 Körner and Contardi [155] Körner and Contardi [156] Brady and R. N. Williams [153] Körner and C ...

338 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES sym-trinitrobenzene results (p. 254). According to Schmidt [147], 2,4,5-trinitro- ben ...

NITRO DERIVATIVES OF TOLUENE 339 Sapoihnikov (according to Gorst [2]) established that the losses of nitric acid during the nitr ...

340 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES The compound cannot be obtained by direct nitration of trinitrotoluene. It was first ...

NITRO DERIVATIVES OF TOLUENE 341 A. F. HOLLEMAN and I. E. VAN D. AREND, Rec. trav. chim. 28, 408 (1909). W. W. JONES and M. RUS ...

K. LEHMSTEDT, Z. ges. Schiess-S’rengstofw., 13, 118 (1918). J. HACKEL, Roczniki Chem. 16, 323 (1936). J. M. BELL, E. B. GORDON, ...

NITRO DERIVATIVES OF TOLUENE 343 T. URBANSKI and I. PILLICH, Wiad. Techn. Uzbr. 43, 79 (1939). A. KOVACHE and H. THIBON, Mén. p ...

344 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES A. M. D. CRAWFORD, Brit. Med. J. II, 430 (1954). M. J. MCCONNELL and R. H. FUNN, J. ...

CHAPTER IX TNT MANUFACTURE TOLUENE TOLULENE is the principal raw material for the manufacture of TNT. It is produced from light ...

346 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES (2) It is carried out at 480-530°C at a pressure of 15 atm in the presence of a Cr 2 ...

TNT MANUFACTURE^447 TABLE 81 Toluene from Toluene from coal petroleum Specific gravity at 15°C Boiling range Colouration with su ...

348 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES Old French process. This process, as described by Pascal [5], was used in France both ...