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NITRO DERIVATIVES OF TOLUENE 309 strongly reinforced by the induction effect of three nitro groups. This is why trinitro- toluen ...

310 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES According to Heinke [104], trinitrotoluene reacts with diazomethane, three molecules ...

NITRO DERIVATIVES OF TOLUENE 311 TABLE 69 Hydrocarbon Molecular proportion or amine, etc. α− trinitrotoluene/second component Me ...

312 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES Kinetics of the nitration of dinitrotoluene to trinitrotoluene............ DINITROTOL ...

NITRO DERIVATIVES OF TOLUENE 313 centration of sulphuric acid from 100 to 92% may be explained by the fact that the concentratio ...

314 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES Orlova [2a] also studied the change in rate of nitration of dinitrotoluene under the ...

NITRO DERIVATIVES OF TOLUENE 315 The overall low solubility of nitro compounds in the acids causes the distribution coefficient ...

316 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES Another important feature in the nitration of dinitrotoluene is the coefficient of di ...

NITRO DERIVATIVES OF TOLUENE 317 ponding to the maximum rate of nitration when the total concentration is higher than in the hom ...

318 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES the volumes of the two phases. The reaction occurs in both phases but the rate in the ...

NITRO DERIVATIVES OF TOLUENE 319 (2) for d= 1.59 g/cm 3 4.4C 7 H 5 (NO 2 ) 3 = 5.47CO 2 + 9.39CO + 6.09H 2 O + 1.63H 2 + 0.03CmH ...

320 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES The results are tabulated (Table 75) and presented in diagrammatic form (Fig. 74). Th ...

NITRO DERIVATIVES OF TOLUENE^321 The sensitiveness of TNT to friction is also very low, but becomes higher when TNT is in the mo ...

322 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES or “phlegmatizing” substances such as ozokerite, bee’s wax or paraffin. The last is t ...

NITRO DERIVATIVES OF TOLUENE 323 do not agree with the German data. They show that chemically pure α− trinitro- toluene is as po ...

324 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES (2) Staying in bed for one or two days. (3) A special diet, consisting of milk, milk ...

An important observation made by Larionovi [128] was that TNT, present in waste waters in a concentration of 25-80 mg/l., lowere ...

326 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES V VI Compound II is highly toxic. It results in the formation of methaemoglobin. The ...

NITRO DERIVATIVES OF TOLUENE^327 136, 137] and their colleagues found that the η− isomer is also formed during the nitration of ...

(^328) CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES ...