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TNT MANUFACTURE^389 UTILIZATION AND NEUTRALIZING OF SULPHITATION LIQUORS The sulphitation liquors contain dinitrotoluenesulphoni ...

390 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES Gornall and R. Robinson [28] suggested reducing sodium dinitrotoluene sulphate (e.g. ...

TNT MANUFACTURE 391 The water may be decolourized by chlorination, but this requires large quan- tities of chlorine. Biological ...

392 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES and soon the nitro compounds on the surface of the spent acid exploded. The explo- si ...

TNT MANUFACTURE 393 flammable, although this occurs under specific conditions of prolonged action of glowing material. Steele [3 ...

394 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES B. KRATZ, Vom Wusser 17. 83 (1949). Mém. poudres 34, 379 (1952). A. KOVACHE and H. T ...

CHAPTER X NITRO DERIVATIVES OF HIGHER BENZENE HOMOLOGUES HIGHER benzene homologues, which have more or longer side chains than t ...

396 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES mixtures. This can be seen in the diagram (Fig. 102) illustrating the nitration ofmix ...

NITRO DERIVATIVES OF HIGHER BENZENE HOMOLOGUES 397 Nitro derivatives of xylene were first mentioned in a work by Bussenius and E ...

398 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES Isomers of trinitro-m-xylene (TNX)........................ The following three isomer ...

NITRO DERIVATIVES OF HIGHER BENZENE HOMOLOGUES^399 Physical properties of 2,4,6-trinitro-m-xylene 2,4,6-Trinitro-m-xylene crysta ...

400 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES 2,4,6-Trinitro-m-xylene forms addition products less easily than α− trinitrotoluene. ...

NITRO DERIVATIVES OF HIGHER BENZENE HOMOLOGUES 401 Then, by oxidizing one of the methyl groups to a carboxyl group with chromic ...

402 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES Mononitro derivatives of o- and p- xylenes.................... Ortho- and p- xylene n ...

NITRO DERIVATIVES OF HIGHER BENZENE HOMOLOGUES^403 which they separated into two isomers - 3,4,5- (or 4,5,6-) and 3,4,6- (or 3.5 ...

404 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES which reacts with sodium sulphite to form a sulpho derivative: The solubility of the ...

NITRO DERIVATIVES OF HIGHER BENZENE HOMOLOGUES^405 Small differences in the boiling points of the xylene isomers make the prepar ...

406 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES o- xylene f. p. -27.1°C m- xylene f. p. -54.8°C p- xylene f. p. +13.2°C Such big diff ...

NITRO DERIVATIVES OF HIGHER BENZENE HOMOLOGUES 407 Nitrating mixture of a composition: HNO 3 18-19% H 2 SO 4 78-79% H 2 O 3% is ...

408 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES loses about 12% in weight. The oily product separated along with water is allowed to ...