Organic Chemistry

Section 10.7 More About the Stereochemistry of SN 2 and SN 1 Reactions 381 The Stereochemistry of Reactions In contrast to the r ...

The difference between the products obtained from an reaction and from an reaction is a little easier to visualize in the case o ...

Section 10.8 Benzylic Halides, Allylic Halides, Vinylic Halides, and Aryl Halides 383 10.8 Benzylic Halides, Allylic Halides, Vi ...

384 CHAPTER 10 Substitution Reactions of Alkyl Halides There are two reasons that vinylic halides and aryl halides do not underg ...

PROBLEM 22 Which alkyl halide would you expect to be more reactive in an reaction with a given nucleophile? In each case, you c ...

386 CHAPTER 10 Substitution Reactions of Alkyl Halides Table 10.6 Summary of the Reactivity of Alkyl Halides in Nucleophilic Sub ...

Section 10.9 Competition Between SN 2 and SN 1 Reactions 387 Therefore, when both reactions occur simultaneously, increasing the ...

(The same substitution product would have been obtained if the reaction had been an reaction.) d. Because a high concentration o ...

Section 10.10 The Role of the Solvent in SN 2 and SN 1 Reactions 389 What percentage of the reaction takes place by the mechanis ...

390 CHAPTER 10 Substitution Reactions of Alkyl Halides SOLVATION EFFECTS The tremendous amount of energy that is provid- ed by s ...

Section 10.10 The Role of the Solvent in SN 2 and SN 1 Reactions 391 Free energy Progress of the reaction reactants are more hig ...

392 CHAPTER 10 Substitution Reactions of Alkyl Halides Table 10.8 The Effect of the Polarity of the Solvent on the Rate of React ...

PROBLEM 27 How will the rate of each of the following reactions change if the polarity of a protic polar solvent is increased? ...

PROBLEM 29 SOLVED Most of the values given throughout this text are values determined in water. How would the values of the foll ...

Section 10.11 Biological Methylating Reagents 395 group in each of these methylating agents is attached to a positively charged ...

396 CHAPTER 10 Substitution Reactions of Alkyl Halides S-ADENOSYLMETHIONINE: A NATURAL ANTIDEPRESSANT S-Adenosylmethionine is so ...

Problems 397 reaction: a two-step mechanism with a carbocation intermediate Relative reactivities of alkyl halides: Both the i ...

398 CHAPTER 10 Substitution Reactions of Alkyl Halides For each of the following reactions, give the substitution products; if ...

Problems 399 Only one bromoether (ignoring stereoisomers) is obtained from the reaction of the following alkyl dihalide with me ...

I n addition to undergoing the nucleophilic substitution reac- tions described in Chapter 10, alkyl halides undergo elimination ...