Science - USA (2022-06-10)

This result represents a rare example of an efficient noncascade Michael addition reac- tion between prochiral nucleophilic and ...

to quantitatively study the product distribution over time using^1 Hand^19 Fnuclearmagnetic resonance (NMR) spectroscopic techni ...

through a single recrystallization (40 g isolated, dr >20:1, er >99:1). The isolated products of these Michael CIDT reacti ...

PHOSPHORUS CHEMISTRY Enantioselective hydrogen-bond-donor catalysis to access diverse stereogenic-at-P(V) compounds Katherine C. ...

the H-bond donor and the sulfinamide group in promoting high enantioselectivity. Whereas sulfinamido urea1a and its thiourea ana ...

groups on phosphorus that could be selec- tively and stereospecifically displaced to afford access to multiple classes of chiral ...

Forbeset al., Science 376 , 1230–1236 (2022) 10 June 2022 4of6 Fig. 3. Scope of enantioselective addition of diisoamylamine to a ...

Forbeset al., Science 376 , 1230–1236 (2022) 10 June 2022 5of6 Fig. 4. Application to the synthesis of chiral P(V) targets.All y ...

In addition to serving as versatile synthetic building blocks, phosphonamidates are often synthetic targets themselves ( 2 , 3 , ...

I was a crafty kid. Not crafty like a fox, but crafty to the point that my parents would come home braced for whatever “artistic ...