Organic Chemistry

Section 17.13 Soaps, Detergents, and Micelles 701 Na+ CO 2 − H 2 O −O 2 C −O 2 C −O 2 C −O 2 C CO 2 − CO 2 − CO 2 − CO 2 − CO 2 ...

acetic acid 702 CHAPTER 17 Carbonyl Compounds I which means “to wipe off.”After the initial introduction of detergents into the ...

acid immediately donates a proton to the amine when the two compounds are mixed. The ammonium carboxylate salt is the final prod ...

acetamide 704 CHAPTER 17 Carbonyl Compounds I 17.15 Reactions of Amides Amides are very unreactive compounds, which is comfortin ...

PROBLEM 29 a. Which of the following reactions would lead to the formation of an amide? b. For those reactions that do form amid ...

706 CHAPTER 17 Carbonyl Compounds I 17.16 Acid-Catalyzed Hydrolysis of Amides When an amide is hydrolyzed under acidic condition ...

Section 17.16 Acid-Catalyzed Hydrolysis of Amides 707 growing bacteria die because they are unable to produce func- tional cell ...

PROBLEM 31 List the following amides in order of decreasing reactivity toward acid-catalyzed hy- drolysis: 17.17 Hydrolysis of ...

acetonitrile Section 17.18 Hydrolysis of Nitriles 709 PROBLEM 33 Primary amines can also be prepared by the reaction of an alkyl ...

710 CHAPTER 17 Carbonyl Compounds I 17.19 Designing a Synthesis IV: The Synthesis of Cyclic Compounds Most of the reactions we h ...

Section 17.20 Synthesis of Carboxylic Acid Derivatives 711 A cyclic ether can also be prepared by an intramolecular electrophili ...

712 CHAPTER 17 Carbonyl Compounds I A carboxylic acid can be converted into an acyl chloride by heating it either with thionyl c ...

Section 17.20 Synthesis of Carboxylic Acid Derivatives 713 3-D Molecule: Adenosine triphosphate Carboxylic acids can also be act ...

714 CHAPTER 17 Carbonyl Compounds I group breaks a phosphoanhydride bond(rather than the bond), so an intermediate is not formed ...

Section 17.20 Synthesis of Carboxylic Acid Derivatives 715 Coenzyme A was discovered by Fritz A. Lipmann (1899–1986). He also wa ...

716 CHAPTER 17 Carbonyl Compounds I NERVE IMPULSES, PARALYSIS, AND INSECTICIDES After a nerve impulse is transmitted between cel ...

Section 17.21 Dicarboxylic Acids and Their Derivatives 717 COH COH HOCOH O HOC COH O HOCCH 2 COH O O HOCCH 2 CH 2 COH O O HOCCH ...

718 CHAPTER 17 Carbonyl Compounds I Tutorial: Common terms pertaining to carboxylic acids and their derivatives PROBLEM 36 a. Pr ...

We have seen that the OH group of a carboxylic acid can be substituted to give a vari- ety of carboxylic acid derivatives. Simil ...

720 CHAPTER 17 Carbonyl Compounds I Summary of Reactions Reactions of acyl halides (Section 17.8) Reactions of acid anhydrides ...