Organic Chemistry

Summary of Reactions 721 Reactions of carboxylic acids (Section 17.14) Reactions of amides (Sections 17.15 and 17.16) Gabriel s ...

722 CHAPTER 17 Carbonyl Compounds I Dehydration of dicarboxylic acids (Section 17.21) + P 2 O 5 O O HO OH O O O CH 3 O 2 CH 3 ...

Problems 723 Name the following compounds: a. e. h. b. f. i. c. g. j. d. What products would be formed from the reaction of b ...

724 CHAPTER 17 Carbonyl Compounds I A compound with molecular formula gives the following IR spectrum. When it undergoes acid-c ...

Problems 725 b. Which of the reactions that do not occur can be made to occur if an acid catalyst is added to the reaction mixtu ...

726 CHAPTER 17 Carbonyl Compounds I Give the products of the following reactions: a. f. b. g. c. h. d. i. e. j. When treated ...

Problems 727 When a compound with molecular formula undergoes acid-catalyzed hydrolysis, one of the products that is isolated g ...

728 CHAPTER 17 Carbonyl Compounds I Show how the following compounds could be prepared from the given starting materials. You c ...

Problems 729 Sulfonamides, the first antibiotics, were introduced clinically in 1934 (Sections 25.8 and 30.4). Show how a sulfo ...

730 CHAPTER 17 Carbonyl Compounds I stable molecule that structurally resembles the transition state. This causes an antibody to ...

I n Section 17.0, we saw that carbonyl com- pounds—compounds that possess a carbonyl group —can be divided into two classes: Cla ...

732 CHAPTER 18 Carbonyl Compounds II In ketosis, a pathological condition that can occur in people with diabetes, the body produ ...

Section 18.1 Nomenclature 733 Notice that the terminal “e”is not removed in hexanedial; the “e”is removed only to avoid two succ ...

734 CHAPTER 18 Carbonyl Compounds II If the compound has both an alkene and an aldehyde functional group, the alkene is cited fi ...

formaldehyde acetaldehyde acetone Section 18.2 Relative Reactivities of Carbonyl Compounds 735 BUTANEDIONE: AN UNPLEASANT COMPOU ...

736 CHAPTER 18 Carbonyl Compounds II 3-D Molecules: Formaldehyde; Acetaldehyde; Acetone 3-D Molecules: 3-Methyl-2-butanone; 2,4- ...

Section 18.3 How Aldehydes and Ketones React 737 Aldehydes and ketones undergo nucleophilic addition reactions with hydride ion ...

738 CHAPTER 18 Carbonyl Compounds II product will notbe stable. Water will be eliminated from the addition product. This is call ...

Section 18.4 Reactions of Carbonyl Compounds with Carbon Nucleophiles 739 Movie: Reactions of Grignard reagents with ketones Whe ...

740 CHAPTER 18 Carbonyl Compounds II Tertiary alcohols are also formed from the reaction of two equivalents of a Grignard reagen ...