Front Matter

Recently, we have adapted the idea of Zhang and Kyler of using adipate as a prosthetic group, but in contrast to these authors ( ...

example) and a carboxylate ending chain should be place somewhere on the hydro- carbon chain of the substrate. To fulfill these ...

16.3.2 Other lipoxygenases Lipoxygenases 5- or 9-specific Beside n-6 LOXs with SBLOX-1 as an archetype, 5- or 9-LOXs (depending ...

With this example it could be broadly concluded that the methodologies developed for the use of SBLOX-1 could be applied to othe ...

16.4 Applications of PUFA hydroperoxides in fine chemistry 16.4.1 Reduction of PUFA hydroperoxides In living cells, PUFA-HPODs a ...

16.4.3 Protection of the hydroperoxide function and obtaining of chiral synthons In 1991, Dussaultet al. reported a method of pr ...

ing 13(S)-HPODE. 1-stearoyl-sn-glycero-3 phosphocholine was first generated by a chemo-enzymatic approach involving lipases. The ...

derivatives (i.e. 8(S),15(S)-diHETE and 5(S),15(S)-diHETE) in a 65 : 35 ratio and in 80 % yield. 5(S),15(S)-diHETE was then puri ...

concentrations. To obtain access to n-6(S)-HPODs, SBLOX-1 is the enzyme of choice; this is due not only to the fact that this en ...

Drouet, P., Thomas, D., Legoy, M.D. (1994), Production of 13(S)-hydroperoxy-9(Z),11(E)-octadecadie- noic acid using soybean lipo ...

Lagocki, J.W., Emken, A.E., Law, J. H., Kezdy, F.J. (1976), Kinetic analysis of the action of soybean lipoxygenase on linoleic a ...

Shoba, S.V., Ramadoss, C.S., Ravindranath, B. (1992), Regiospecific hydroperoxidation of anacardic acid (15 : 2) by soybean lipo ...

Miscellaneous Enzymes Enzymesin LipidModification.Editedby UweT. Bornscheuer Copyright 2000 Wiley-VCHVerlagGmbH& Co. KGaA,W ...

17 Enzymatic Synthesis and Modification of Glycolipids Siegmund Lang, Christoph Syldatk and Udo Rau 17.1 Enzymatic synthesis of ...

tem. Bearing in mind that the conformational mobility of the enzyme is dependent on the bound-water content, the most suitable a ...

tion medium. Using finallyn-hexane, supercritical carbon dioxide, or even the fatty acid to be esterified, the sugar substrates ...

366 17 Enzymatic Synthesis and Modification of Glycolipids Table 1. Lipase-catalyzed glycolipid syntheses in a) organic solvents ...

17.2 Lipase- and protease-catalyzed esterification of lipids 367 Table 1. Lipase-catalyzed glycolipid syntheses in a) organic so ...

the case of glucose, maltose, trehalose or sucrose, only the primary 6–and/or 6’- positions were acylated. A regioselective acyl ...

17.2 Lipase- and protease-catalyzed esterification of lipids 369 Table 2. Lipase-catalyzed glycolipid syntheses in the presence ...