Physical Chemistry Third Edition

1362 Index Excess enthalpy, 277 Excess entropy, 277 Excess Gibbs energy, 277 Exchange current, of electrodes, 600 Excited states ...

Index 1363 normalization, 697–698 position measurements, 699–700 predictable case and statistical case, 698–699 probabilities an ...

1364 Index Gibbs energy (G), 151, 153 calculations of, 175–180 ideal gas, 175–176 real gas, 175–176 solids and liquids, 178 temp ...

Index 1365 relative speed, 427–428 total rate of collisions, 429–430 pressure of, 424 self-diffusion in, 460–464, 461f analysis ...

1366 Index Heteronuclear diatomic molecules, 851–865 bonding qualitative description, 859–861, 860f electronegativity, 862–863, ...

Index 1367 heat capacity of at constant pressure, 75 at constant volume, 61 internal pressure, 168–169 Joule–Thomson experiment, ...

1368 Index Isosurface, orbital region, 747 Isothermal compressibility, 17 of first-order phase transitions, 217, 217f heat capac ...

Index 1369 chemical reactions of homogenous catalysis of, 574–575 involving gases, 310–313 rates of, 527–528 classical statistic ...

1370 Index Mathematics (cont.) problem solving techniques, 9–11 for quantum mechanics, 1275–1281 Matrices, 1249–1251 determinant ...

Index 1371 method of intercepts for, 193 in nonideal solutions, 276 state and, 87 Molar enthalpy change of vaporization, in boil ...

1372 Index Multicomponent systems (cont.) phase equilibrium of phase diagrams for, 237 surfaces in, 230–234 Multielectron atoms ...

Index 1373 nth-order reactions, 493–494 half-life, 496 integrated rate laws, 495, 495f method of initial rates, 497, 497f rate l ...

1374 Index Partial molar quantities (cont.) in nonideal solutions, 275–276 in one-component ideal gas, 186–187 in one-component ...

Index 1375 hydrogen reaction with other halogens, 559–560 laws of, 558–559 Photoelectric effect, Einstein’s theory of, 645 Photo ...

1376 Index Probability density (cont.) for excited state, 773 of harmonic oscillator, 703–704, 703–704f for helium, 794–795 orbi ...

Index 1377 Raman, Chandrasekhara Venkata, 985 Raman shift, 986 Raman spectrophotometer, 985, 985f Raman spectroscopy, 949, 985–9 ...

1378 Index Redlich–Kwong equation of state, 23, 23t for fluid surface, 30f, 31 Reduced coordinate distribution function, 1148 Re ...

Index 1379 for hydrogen atom, 725–726 relative angular momentum values, 733–736, 735f theΦfunctions, 731–732 first separation of ...

1380 Index Solute(s), 249 activity of, 315 colligative properties of, 292–298 boiling point elevation, 295–296 freezing point de ...

Index 1381 Spontaneous processes, in closed systems, 152–154, 195 Square integrable, function, 1256 Square matrix, 1249 Square w ...